There are, however, certain minutiæ of the hydrogen spectrum
which cannot be explained by Bohr’s theory in its original form.
All these, down to the smallest particular, are explained by the
generalized form of the theory which is due in the main to Sommerfeld.
We shall explain this generalized theory in the next chapter.
The quantity , Planck’s quantum, has been found to be involved in
all the very minute phenomena that can be adequately studied. It is one
of the fundamental constants to which science is led: for the present,
it represents a limit of explanations, since no one knows why there
[Pg 71]
is such a constant or why it is just the size it is. The limits of our
explanations in any given stage of science are, while that stage lasts,
brute facts; and so Planck’s quantum, for the present, is a brute fact.
It is involved in all very small periodic processes; but why this
should be the case we do not know.
[3]
Expressed in the usual C.G.S. units,
. Its dimensions are those of action or
angular momentum.
[4]
For the mathematical statement of the principle, see
Sommerfeld’s Atomic Structure and Spectral Lines, 3rd ed.,
translated by Henry L. Brose M. A. (Dutton, New York) Chap. IV. and
Appendix 7.
[5]
See Appendix.
[Pg 72]
VII.
REFINEMENTS OF THE HYDROGEN SPECTRUM
IN Bohr’s theory, the electron always moves round the hydrogen nucleus
in a circle. But according to Newtonian principles, the electron
ought also to be able to move in an ellipse, and the generalized
quantum-principle can be applied to elliptic orbits as well as to those
that are circular. It is natural to inquire whether it is possible to
work out a theory that allows for elliptic orbits, and, if so, whether
it will fit the facts better or worse than Bohr’s original theory.
It is found that, as regards the broad facts, it makes no difference
whether we admit or reject elliptic orbits; in either case, the facts
will accord with observation to a first approximation. There are,
however, three delicate phenomena which are observed to occur, which
cannot be accounted for if all the possible orbits are circles, but are
to be expected if ellipses also occur. These are the following: First,
there is what is called the Zeeman effect, which is an alteration
[Pg 73]
produced by a strong magnetic field. Secondly, there is the Stark
effect, which is produced by a strong electric field. Thirdly, there
is what is called the “fine structure,” which is the fact that each
single line of the spectrum, when very closely examined, is found to
consist of a number of almost identical lines. The explanation of the
Zeeman effect is still in part incomplete, but the explanation of the
other two by means of Sommerfeld’s methods is as perfect as could be
desired. We shall not attempt to set forth the explanation, which would
be impossible without a good deal of mathematics. We shall only attempt
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