Bohr's theory has been generalized by Wilson[12] and Sommerfeld so as
to allow also elliptic orbits: these have two quantum numbers, one
corresponding, as before, to angular momentum or the moment of momentum
(which is constant, by Kepler's second law), the other depending upon
the eccentricity. Only certain eccentricities are possible; in fact,
the ratio of the minor to the major axis is always rational, and has
as its denominator the quantum number corresponding to the moment of
momentum. In order to explain the Zeeman effect (which arises in a
magnetic field) we used a third quantum number, corresponding to the
angle between the plane of the magnetic field and the plane of the
electron's orbit. In all cases, however, there is a general principle,
which must now be explained. This will show, also, why, in Bohr's
theory, the quantum equation (2) takes the form it does.[13]
The first thing to observe is that the quantum principle is really
concerned with atoms of action, not of energy: action is energy
multiplied by time. Suppose now that we have a system depending
upon several co-ordinates, and periodic in respect of each. It is
not necessary to suppose that each co-ordinate has the same period:
it is only necessary to suppose that the system is "conditionally
periodic"—i.e. that each co-ordinate separately is periodic.
We must further assume that our co-ordinates are so chosen as to
allow "separation of variables" (as to which, see Sommerfeld, op.
cit., pp. 559-60). We then define the "momentum" (in a generalized
sense) associated with the co-ordinate as the partial
differential of the kinetic energy with respect to —i.e.
calling the generalized momentum , we put:
where is the kinetic energy. The quantum condition
is to apply to the integral of over a complete period of
—i.e. we are to have:
where the integration is taken through one complete period of .
Here will be the quantum number associated with the co-ordinate
. The above is a general formula of which all known cases of
quantum phenomena are special cases. This is its sole justification.
The above principle is exceedingly complicated—more so, even, than it
appears in our summary account, which has omitted various difficulties.
It is possible that its complication may be due to the fact that
quantum dynamics has had to force its way through the obstacles which
the classical system put in its way; it is possible also that quantum
phenomena may turn out to be deducible from classical principles. But
before pursuing this line of thought, it may be well to say[Pg 37] a few
words about the developments of Bohr's theory by Sommerfeld and others.
Public-domain text, read in full here on John Shaqi.
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