In its original form, in which circular orbits were assumed, Bohr's
theory accounted for the main facts concerning the line spectra of
hydrogen and ionized helium. But there were a number of more delicate
facts which required the hypothesis of elliptic orbits: with this
hypothesis, together with some niceties derived from relativity, the
most minute agreement has been obtained between theory and observation.
But perhaps this great success has made people think that more was
proved than really was proved. The great advantage obtained from
admitting elliptic orbits is that they provide a second quantum number.
In the emission of light by atoms, what we have is essentially as
follows. The atom is capable of various states, characterized by whole
numbers (the quantum numbers). There may be more or fewer quantum
numbers, according to the degrees of freedom of the system. The loss
or gain of energy when an atom passes from a state characterized by
one set of values of the quantum numbers to a state characterized by
another set is known. When energy is lost (without the loss of an
electron or of any part of the nucleus of the atom), it passes out as a
light-wave, whose energy is equal to what the atom has lost, and whose
energy multiplied by the time of one vibration is . Energy is what
is conserved, but action is what is quantized.
Let us revert, in illustration, to the circular orbits of Bohr's
original theory, which remain possible, though not universal, in the
newer theory. If we call the kinetic energy when the
electron is in the smallest possible orbit, the kinetic energy in the
orbit is . (The measure of the total
energy is the kinetic energy with its sign changed.) We do not know
what determines the electron to jump from one orbit to another; on this
point, our knowledge is merely statistical.[Pg 38] We know, of course, that
when the atom is not in a position to absorb energy the electron can
only jump from a larger to a smaller orbit, while the converse jump
occurs when the atom absorbs energy from incident light. We know also,
from the comparative intensities of different lines in the spectrum,
the comparative frequencies of different possible jumps, and on this
subject a theory exists. But we do not know in the least why, of a
number of atoms whose electrons are not in minimum orbits, some jump at
one time and some at another, just as we do not know why some atoms of
radio-active substances break down while others do not. Nature seems
to be full of revolutionary occurrences as to which we can say that,
if they take place, they will be of one of several possible
kinds, but we cannot say that they will take place at all, or, if they
will, at what time. So far as quantum theory can say at present, atoms
might as well be possessed of free will, limited, however, to one of
several possible choices.[14]
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