However this may be, it is clear that what we know is the changes
of energy when an atom emits light, and we know that in the case
of hydrogen or ionized helium these changes are measured by
. It seems almost unavoidable to
infer that the previous state of the atom was characterized by the
integer and the later one by the integer . But to assume
orbits and so on, though proper as a help to the imagination, is hardly
sufficiently justified by the analogy of large-scale processes, since
the quantum principle itself shows the danger of relying upon this
analogy. In large-scale occurrences there is nothing to suggest the
quantum, and perhaps other familiar features of such occurrences may
result merely from statistical averaging.
[Pg 39]
It may be worth while to consider briefly the elliptical orbits which
are possible.[15] This will also illustrate the application of the
quantum principle to systems with more than one co-ordinate.
Taking polar co-ordinates, the kinetic energy is:
The two generalized momenta are therefore:
We have thus two quantum conditions:
By Kepler's second law, is constant; call it
. Thus:
The other integration is more troublesome, but we arrive at the result
that, if and are the major and minor axes of the ellipse,
A little further calculation leads to the result that the energy
in the orbit which has the quantum numbers , is:
This is exactly the same as in the case of circular orbits, except
that replaces . If this were all, the line spectrum of
hydrogen would be exactly the same whether elliptic orbits occurred or
not, and there would be no empirical means of deciding the question.
However, by introducing considerations derived from the special
theory of relativity we are able to distinguish between the results
to be expected from circular and elliptic orbits[Pg 40] respectively, and
to show that the latter must occur to account for observed facts.
The crucial point is the variation of mass with velocity: the faster
a body is moving, the greater is its mass. Therefore in an elliptic
orbit the electron will have a greater mass at the perihelion than
at the aphelion. From this it is found to follow that an elliptic
orbit will not be accurately elliptic, but that the perihelion will
advance slightly with each revolution.[16] That is to say, taking polar
co-ordinates , , the co-ordinate increases
by slightly more than between one minimum of and the next.
The system is thus "conditionally periodic"—i.e. each separate
co-ordinate changes periodically, but the periods of the two do not
coincide. The result[17] is that the equation
is replaced by:
being the velocity of light, and , as before, the angular
momentum. It will be seen that is very nearly 1, because
is large.
Public-domain text, read in full here on John Shaqi.
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