The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
While Dalton’s theory could not give information about the absolute
weights in grams of the atoms of various elements, it could say
something about the relative atomic weights, _i.e._, the ratios of
the weights of the different kinds of atoms, although it is true that
these ratios could not always be determined with certainty. If, for
example, the ratio between the oxygen and hydrogen in water is found
to be as eight to one, then the weight ratio between the oxygen atom
and the hydrogen atom will be as eight to one, if the water molecule is
composed of one oxygen atom and one hydrogen atom (as Dalton supposed,
see Fig. 2). But it will be as sixteen to one, if the water molecule is
composed of one oxygen and two hydrogen atoms (as we now know to be the
case). On the other hand, a ratio of seven to one will be compatible
with the experimental ratio of eight to one only if we assume that the
water molecule consists of fifteen atoms, eight of oxygen and seven of
hydrogen, a very improbable hypothesis. In another case let us compare
the quantities of oxygen and of hydrogen which are compounded with the
same quantities of carbon in the two substances, carbon monoxide and
methane respectively. On the assumption that the molecules in question
have a simple structure, we can draw conclusions about the ratio of the
atomic weights of hydrogen and oxygen. Now, if a ratio such as seven
to one or fourteen to one is obtained while the analysis of water
gives eight to one or sixteen to one, then either the structure of the
molecule is more complicated than was assumed, or the analyses must be
improved by more careful experiments. We can thus understand that the
atomic theory can serve as a controlling influence on the analysis of
chemical compounds.
In order to choose between the different possible ratios of atomic
weights, for example, the eight to one or the sixteen to one in the
case of oxygen and hydrogen, Dalton had to make certain arbitrary
assumptions. The first of these is that two elements of which only
one compound is known appear with but one atom each in a molecule.
Partly on account of this assumption and partly on account of the
incompleteness of his analyses, Dalton’s values of the ratios of the
atomic weights of the atoms and his pictures of the structure of
molecules differ from those of the present day, as is obvious from Fig.
2.
A much firmer foundation for the choice made appears later in the
_Avogadro Law_; starting with the fact that different gases show
great similarity in their physical conduct—for instance, all expand by
an increase of ¹⁄₂₇₃ of their volume with an increase in temperature
from 0° C. to 1° C.—the Italian, Avogadro, in 1811, put forward the
hypothesis that equal volumes of all gases at the same temperature and
pressure contain equal numbers of molecules. A few examples suffice to
show the usefulness of this rule.
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