The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
When one volume of the gas chlorine unites with one volume of hydrogen
there result two volumes of the gas, hydrogen chloride, at the same
temperature and pressure. According to Avogadro’s Law one molecule of
chlorine and one molecule of hydrogen unite to become two molecules of
hydrogen chloride, and since each of these two molecules must contain
at least one atom of hydrogen and one atom of chlorine, it follows
that one molecule of chlorine must contain two atoms of chlorine and
that one molecule of hydrogen must contain two atoms of hydrogen. From
this one can see that even in the elements the atoms are united into
molecules. It is now well established that most elements have diatomic
molecules, though some, including mercury and many other metals, are
monatomic. When oxygen and hydrogen unite to form water, one litre of
oxygen and two litres of hydrogen produce two litres of water vapour at
same temperature and pressure. Accordingly, one molecule of oxygen and
two molecules of hydrogen form two molecules of water. If the oxygen
molecule is diatomic like the hydrogen, then one molecule of water
contains one atom of oxygen and two atoms of hydrogen. Since the weight
ratio between the oxygen and hydrogen in water is eight to one, the
atomic weight of oxygen must be sixteen times that of hydrogen.
Through such considerations, supported by certain other rules, it has
gradually proved possible to obtain reliable figures for the ratios
between the atomic weights of all known elements and the atomic weight
of hydrogen. For convenience it was customary to assign the number 1 to
the latter and to call the ratio between the weight of the atom of a
given element and the weight of the hydrogen atom the atomic weight of
the element in question. Thus the atomic weight of oxygen is 16, that
of carbon 12, because one carbon atom weighs as much as 12 hydrogen
atoms. Nitrogen has the atomic weight 14, sulphur 32, copper 63.6, etc.
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