The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
A summary of the chemical properties and chemical compounds was greatly
facilitated by the symbolic system initiated by the Swedish chemist,
Berzelius. In this system the initial of the Latin name of the element
(sometimes with one other letter from the Latin name) is made to
indicate the element itself, an atom of the element, and its atomic
weight with respect to hydrogen as unity, while a small subscript to
the initial designates the number of atoms to be used. For example, in
the chemical formula for sulphuric acid, H₂SO₄, the symbolic formula
means that this substance is a chemical compound of hydrogen, sulphur
and oxygen, that the acid molecule consists of two atoms of hydrogen,
one atom of sulphur and four atoms of oxygen, and that the weight
ratios between the three constituent parts is as 2×1 = 2 to 32 to 4×16
= 64, or as 1:16:32. To say that the chemical formula of zinc chloride
is ZnCl₂ means that the zinc chloride molecule consists of one atom of
zinc and two atoms of chlorine. Furthermore the changes which take
place in a chemical process may be indicated in a very simple way. Thus
the decomposition of water into hydrogen and oxygen may be represented
by the so-called chemical “equation” 2H₂O ⇾ 2H₂+O₂, where H₂ and O₂
signify the molecules of hydrogen and oxygen respectively. Conversely,
the combination of hydrogen and oxygen to form water will be given by
the equation 2H₂+O₂ ⇾ 2H₂O.
As a consequence of the development of the atomic theory the atoms of
the elements became, so to speak, the building stones of which the
elements and the chemical compounds are built. It can also be said that
the atoms are the smallest particles which the chemists reckon with in
the chemical processes, but it does not follow from the theory that
these building stones in themselves are indivisible. The theory leaves
the way open to the idea that they are composed of smaller parts. A
belief founded on such an idea was indeed enunciated by the Englishman,
Prout, a short time after Dalton had developed his atomic theory.
Prout assumed that the hydrogen atoms were the fundamental ones, and
that the atoms of the other elements consisted of a smaller or larger
number of the atoms of hydrogen. This might explain the fact that
within the limits of experimental error, many atomic weights seemed
to be integral multiples of that of hydrogen—16 for oxygen, 14 for
nitrogen, and 12 for carbon, etc. This led to the possibility that the
same might hold for all elements, and this hypothesis gave impetus to
very careful determinations of atomic weights. These, however, showed
that the assumption of the integral multiples could not be verified. It
therefore seemed as if Prout’s hypothesis would have to be given up. It
has, however, recently come into its own again, although the situation
is more complicated than Prout had imagined (see p. 97).
Public-domain text, read in full here on John Shaqi.
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