The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
As mentioned above, one atom of oxygen combines with two atoms of
hydrogen to form water, while one atom of chlorine combines with but
one atom of hydrogen to form hydrogen chloride. The oxygen atom thus
seems to be “equivalent” to two hydrogen atoms or two chlorine atoms,
while one chlorine atom is “equivalent” to one hydrogen atom. The atoms
of hydrogen and chlorine are for this reason called monovalent, while
that of oxygen is called divalent. Again an acid is a chemical compound
containing hydrogen, in which the hydrogen can be replaced by a metal
to produce a metallic salt. Thus, when zinc is dissolved by sulphuric
acid to form hydrogen and the salt zinc sulphate, the hydrogen of the
acid is replaced by the zinc and the chemical change may be expressed
by the formula
Zn+H₂SO₄ ⇾ H₂+ZnSO₄
In this, one atom of zinc changes place with two atoms of hydrogen. The
zinc atom is therefore divalent. This is consistent with the fact that
one zinc atom will combine with one oxygen atom to form zinc oxide. To
take another example, if silver is dissolved in nitric acid, one atom
of silver is exchanged for one atom of hydrogen. Silver, therefore, is
monovalent, and we should expect that one atom of oxygen would unite
with two atoms of silver. Some elements are trivalent, as, for example,
nitrogen, which combines with hydrogen to form ammonia, NH₃; others,
again, are tetravalent, such as carbon, which unites with hydrogen
to form marsh gas CH₄, and with oxygen to form carbon dioxide CO₂. A
valence greater than seven or eight has not been found in any element.
[Illustration: FIG. 3.—Rough illustrations of the valences of
the elements.
A. Hydrogen chloride (HCl); B. Water (H₂O); C. Methane (CH₄); D.
Ethylene (C₂H₄).]
If we consider the matter rather roughly and more or less as Gassendi
did, we can explain the concept of valence by assuming that the atoms
possess hooks; thus hydrogen and chlorine are each furnished with one
hook, oxygen and zinc with two hooks, nitrogen with three hooks, etc.
When a hydrogen atom and a chlorine atom are hooked together, there
are no free hooks left, and consequently the compound is said to be
saturated. When one hydrogen atom is hooked into each of the hooks of
an oxygen or carbon atom the saturation is also complete (see Fig. 3,
A, B, C).
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