The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
The matter is not so simple as this, however, since the same element
can often appear with different valences. Iron may be divalent,
trivalent or hexavalent in different compounds. In many cases,
however, where an examination of the weight ratios seems to show that
an element has changed its valence, this is not really true. It was
mentioned previously that carbon forms another compound with hydrogen
in addition to CH₄, namely, ethylene, containing half as much hydrogen
in proportion to the same amount of carbon. With the aid of Avogadro’s
Law, it is found that the ethylene molecule is not CH₂ but C₂H₄. Thus
we can say that the two carbon atoms in the molecule are held together
by two pairs of hooks, and consequently the compound can be expressed
by the formula
H-C-H
‖
H-C-H
where the dashes correspond to hooks (cf. Fig. 3, D). Such a formula is
called a _structural formula_.
Even if we are not allowed to think of the atoms in the molecules
as held together by hooks, it is well to have some sort of concrete
picture of molecular structure. It is possible to represent the
tetravalent carbon atom in the form of a tetrahedron, and to consider
the united atoms or atomic groups as placed at the four vertices. With
such a spatial representation we can get an idea about many chemical
questions which otherwise would be difficult to explain. We know, for
example, that two compound molecules having the same kind and number of
atoms and the same bonds (and hence the same structural formulæ), may
yet be different in that they are images of each other like a pair of
gloves. Substances whose molecules are symmetrical in this way can be
distinguished from each other by their different action on the passage
of light. This molecular chemistry of space, or stereo-chemistry as
it is called, has proved of great importance in explaining difficult
problems in organic chemistry, _i.e._ the chemistry of carbon.
Although there have never been many chemists who really have believed
the carbon atom to be a rigid tetrahedron, we must admit that in this
way it has been possible to get on the track of the secrets of atomic
structure.
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