The atom and the Bohr theory of its structure : $b an elementary presentationHolst, Helge
Science
The atom and the Bohr theory of its structure : $b an elementary presentation
Holst, Helge
Atomic theory
Then the radiation actually emitted should, according
to the correspondence principle, be such that the intensities of the
lines corresponding to the double and triple jumps, which start from a
given stationary state, are respectively one-half and one-third of the
intensity corresponding to a single jump from the same state.
By these examples we can obtain an idea of how the correspondence
principle may in certain cases account for various facts, as to what
spectral lines cannot be expected to appear at all, although they would
be given by a particular transition, and concerning the distribution
of intensities in those which really appear. The illustration given
above, however, has really nothing much to do with actual problems, and
objections may be raised to the rough way in which the illustration has
been handled. The correspondence principle has its particular province
in more complicated electron motions than those which appear in the
unperturbed hydrogen atom—motions which, unlike the simple elliptical
motion, are not composed of a series of harmonic oscillations (ω, 2ω,
3ω ...) but may be considered as compounded of oscillations whose
frequencies have other ratios. The correspondence principle has, in
such cases, given rise to important discoveries and predictions which
agree completely with the observations.
We have dwelt thus long upon the difficult correspondence principle,
because it is one of Bohr’s deepest thoughts and chief guides. It has
made possible a more consistent presentation of the whole theory, and
it bids fair to remain the keystone of its future development. But from
these general considerations we shall now proceed to more special
phases of the problem and examine one of the first great triumphs in
which the theory showed its ability to lead the way where previously
there had been no path.
The False Hydrogen Spectrum.
In 1897 the American astronomer, Pickering, discovered in the spectrum
of a star, in addition to the usual lines given by the Balmer series, a
series of lines each of which lay about midway between two lines of the
Balmer series; the frequencies of these lines could be represented by a
formula which was very similar to the Balmer formula; it was necessary
merely to substitute _n_ = 3½, 4½, 5½, etc., in the formula on
p. 57 instead of _n_ = 3, 4, 5, etc. It was later discovered
that in many stars there was a line corresponding to _n″_ = ³/₂
or _n′_ = 2 in the usual Balmer-Ritz formula (p. 59). It was
considered that these must be hydrogen lines, and that the spectral
formula for this element should properly be written
1 1
ν = K ---------- - ---------
( _n″_/2 )² ( _n′_/2 )²
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account