The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
It worked! The faulty plastic contains 100 times as much copper as the
good plastic, specifically 100 parts per million. (If 0.1 milligrams of
pure copper gave 1,000,000 counts, then the 0.1 grams of faulty plastic
contains (100,000/1,000,000) · 0.1 milligrams or 0.01 milligrams of
copper. This is one ten thousandth of the weight of the plastic or 0.01%
or 100 ppm.) You relay the information to the plant superintendent
almost before he finishes his lunch. He now knows what to do and the
crisis is over.
In a Museum
_The Problem_
You are a curator working with the ancient coin collection of a large
museum. A donor has just given the museum a group of 50 gold coins
presumably about 1500 years old. After months of careful study, you have
satisfied yourself that most of those coins are genuine specimens of
that period. Judging from your experience, you decide that a small group
of five are definite forgeries.
However, there are three others that you suspect are also fakes, but you
are not quite certain. You know that both genuine minters and forgers
often tried to save money by diluting their gold with less expensive
metals such as silver and copper. Since the chances are slim that the
forger’s product has the same concentration of gold, silver, and copper
as the genuine coins, you realize that a chemical analysis would help
you decide if the doubtful pieces were real or fake.
An accurate chemical analysis would require a sample of such size that
the coin would be ruined as a museum specimen. You need an analytical
method that can be applied to an infinitesimal sample.
_The Solution_
You are not a scientist but you’ve heard about neutron activation
analysis. Therefore, you contact a radiochemist at a local university
who is an expert in this field.
He decides to use a sampling technique developed by scientists at
Brookhaven National Laboratory for sampling metal objects of
archaeological interest. You obtain from him a set of 50 quartz plates
that have been ground on one side. Following his instructions, you
carefully scrape away a small area on the edge of each coin. You then
rub each freshly cleaned area across the ground surface of one plate
leaving a minute streak of metal similar to a pencil mark.
At the scientist’s laboratory, each plate is carefully placed inside a
quartz tube. No attempt is made to weigh the tiny streak of metal since
you wish only to compare the ratios of the metal concentrations.
However, because the samples make a rather bulky package, the scientist
is concerned with the uniformity of the neutron flux that each sample
will “see”. He therefore also places in each tube an exactly equal
weight of a gold—silver—copper alloy wire (of known proportions) to act
as a standard neutron-flux monitor. The tubes are then sealed and taken
to a reactor to be irradiated for 12 hours.
Public-domain text, read in full here on John Shaqi.
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