The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
After the samples are removed from the reactor, the scientist carefully
breaks open each of the quartz tubes and places the sample and the
standard piece of wire in separate numbered plastic capsules with lids.
For an accurate comparison, each capsule is prepared in the same manner.
About 4 hours after the samples are removed from the reactor, he begins
the radioactivity measurements.
The sample capsules are loaded into an automatic sample-changing
mechanism that places each one into an identical position above a
lithium-drifted germanium detector. (See the chapter beginning on page
19.) Gamma-ray spectra are collected all day, first from a sample, then
from its accompanying standard. Each count takes 2 minutes, and 3
minutes are required between counts for data printout and sample
changing. A typical gamma-ray spectrum looks like the one in the figure
on the next page. Notice that only gold (gold-198) and copper
(copper-64) show up in this short counting time. Later on, radioactivity
from silver (silver-110_m_) can be measured using a longer counting
time. This can be done because while the activation products from copper
and gold have relatively short half-lives (12.8 hours and 2.7 days,
respectively), that from silver has a half-life of 270 days. To increase
the sensitivity of the analysis for silver, the scientist repackages and
re-irradiates the samples and wires for 100 hours. Silver-110_m_ is one
of _two_ radioactive isotopes of silver that have the _same_ mass. In
this case, one has a higher energy than the other and decays in a
different way. This is known as an isomeric state and it occurs for many
other elements as well as for silver.
[Illustration: Graph: “Counts in one minute per 3.1 KeV channel” _vs_
“Channel”]
Element Counts Channel number
0.158 MsV Au-199 600 40
0.412 MeV Au-198 800 120
0.511 MeV Cu-64 50 150
0.676 MeV Au-198 40 205
(Values estimated from graph)
The spectrum obtained from a streak of metal on a quartz plate after a
3-hour exposure to neutrons in a reactor and a 6-hour delay before
counting. The activation products of gold and copper are obviously
present and are easily measured in only 1 minute.
[Illustration: Graph: “Counts per 100 minutes per 3.2 KeV channel” _vs_
“Channel number”]
Public-domain text, read in full here on John Shaqi.
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