The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
Energy Counts Channel Number
0.445 MeV 230 130
0.657 MeV 1200 190
0.687 MeV 170 200
0.715 MeV 220 220
0.760 MeV 230 225
0.820 MeV 60 250
0.884 MeV 500 260
0.937 MeV 190 280
(Values are estimated from graph)
The spectrum obtained from the same streak of metal after re-exposure
to neutrons for 100 hours and a delay of approximately 2 months before
counting. Activation products from gold and copper have decayed away
and the gamma-ray spectrum of silver-110m is now observed. In this
case the sample is closer to the detector than for the earlier
measurement and the measurement takes 100 minutes.
Two months later, the scientist repeats the procedure of counting the
samples and standards, except that this time the plastic capsules are
closer to the detector, each count is for 100 minutes, and the sample
changer operates for about a week. A typical spectrum looks like that in
the figure on page 39.
The scientist can now compute ratios for the three elements in each
sample and compare them with the standard, but he decides that a
computer could do it faster and with fewer errors. The data collected
during the two series of counts are therefore sent to a data processing
center where, in a matter of minutes, a computer does the following for
each of 50 samples:
1. Finds the 0.411-MeV gamma-ray peak for gold-198.
2. Determines the total counts in the peak.
3. Repeats the process for the corresponding wire standard.
4. Corrects the total count for the wire for the small amount of
radioactive decay that occurred in the few minutes between the sample
count and the standard count.
5. Computes the ratio: [total count for sample/total count for
standard (corrected)]
6. Repeats all the above for the 0.511-MeV gamma ray for copper-64 and
(in the longer counts) for the 0.658-MeV gamma ray for silver-110.
7. Computes the ratios: [sample to standard (for copper)/sample to
standard (for gold)] and [sample to standard (for silver)/sample to
standard (for gold)].
8. Tabulates and prints the ratios found in Step 7.
[Illustration: Graph: Number of coins at indicated ratios vs.
Copper/gold ratio]
Public-domain text, read in full here on John Shaqi.
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