The Atomic Fingerprint: Neutron Activation Analysis — John Shaqi
The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
1. The cross section of the target element.
2. The half-life of the radioactive isotope produced.
3. The time available for irradiation.
4. The flux of neutrons available for irradiation.
5. The promptness with which we can begin measuring radioactivity and
the efficiency of this measurement.
6. Possible interferences due to the presence of elements yielding the
same radioactive elements or those yielding very similar
radiations.
In the next section of this booklet, there are several examples that
will show you how all this works in practice. But to summarize what
these factors mean in terms of sensitivity let us look at the chart in
the figure on page 18. Here all the elements are arranged in a periodic
table. The sensitivities are shaded in coded ranges representing
measurable quantities. They are calculated on the basis that there are
no interferences, that the neutron flux is 10¹⁴ neutrons per square
centimeter per second, and that we can measure 100 gamma rays per minute
without much difficulty assuming a gamma-ray detector efficiency[7] of
10%. The elements labeled β yield radioisotopes that emit few or no
gamma rays and can only be analyzed by neutron activation using
appropriate chemical separation procedures followed by beta
radioactivity measurements. Such chemical separation procedures (to
remove unwanted radioactive isotopes of other elements) are also
sometimes useful to improve the sensitivity of the analysis of gamma-ray
emitters if necessary.
[Illustration: Graph: “Fraction of Sodium-24 remaining” vs. “Time of
decay (hours)”]
The radioactive decay curve of sodium-24. The vertical scale is not
_linear_ but _logarithmic_. Thus, each factor of two in radioactivity
occupies the same distance along the vertical axis. When two samples
are being analyzed for sodium by activation analysis, they must be
compared at the same time after they have been removed from the
neutron flux. If this period of time is different, then a correction
must be applied to one of them, based on the decay curve shown here,
to allow for the difference in decay time for the two. Waiting too
long after the irradiation is completed results in much poorer
sensitivity for the analysis depending on the half-life of the
activation product. In this case, after 2 days it takes approximately
ten times as much sodium to yield the same radioactivity as it would
if the sample were measured when it was fresh out of the reactor.
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