The Atomic Fingerprint: Neutron Activation AnalysisKeisch, Bernard
Science
The Atomic Fingerprint: Neutron Activation Analysis
Keisch, Bernard
Nuclear activation analysis
It is not practical to determine a few elements, shown in black squares,
by activation analysis. Some others, like oxygen and nitrogen (labeled
HE), can be measured by using other projectiles like fast (more
energetic) neutrons, or protons or deuterons[8] produced in a device
called an accelerator. Other elements, those shown in white squares, can
be detected with such great sensitivity, that one can find some in
almost everything. For example, if you had a cube of “pure” aluminum
only 1 millimeter on a side, you could detect gold in it if there were
only one atom of gold for every fifty billion atoms of aluminum.
While it isn’t often that you would want to find a gold needle in an
aluminum haystack, the next section presents some practical
applications. Imagine yourself as the person with the problem in these
situations.
[Illustration: Periodic table of elements, with sensitivity code]
* Th and U are radioactive but with such long half-lives that
neutron activation analysis can be used for their determination.
† µg = Microgram (one-millionth of a gram)
HOW AND WHERE TO USE IT
In a Physics Laboratory
_The Problem_
You are a physicist investigating the properties of semiconductors,
which are materials used to make transistors. When you apply a voltage
to one specimen of silicon (a semiconductor), it doesn’t behave quite
like the others that you’ve studied. The electrical properties of this
odd specimen are unusual and interesting and could lead to a new type of
transistor. What makes this specimen different from the others? Very
small amounts of impurities can cause large changes in the electrical
properties of semiconductors. You would like to obtain a chemical
analysis of the material, but your colleagues in chemistry tell you they
would have to dissolve a good size part of your sample to analyze it and
you are reluctant to give it up. How do you do it?
_The Solution_
You decide to try neutron activation analysis. You realize you won’t be
able to detect all the elements, but many of those that might affect
semiconductor performance could be detected quite easily.
Public-domain text, read in full here on John Shaqi.
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