The Chemical Constituents of Piper Methysticum: Or, The Chemical Constituents of the Active Principle of the Ava RootBall, Alice A.
Science
The Chemical Constituents of Piper Methysticum: Or, The Chemical Constituents of the Active Principle of the Ava Root
Ball, Alice A.
Kava plant
The oxidation product contains at least three distinct substances,
benzoic acid, a substance melting at 200 degrees and—which is probably
p-acetyl benzoic acid and a third substance melting at 110 degrees.
_THE IRON ACIDS._
The resinous material used and spoken of as the IRON ACIDS is the
material prepared and so named under the “Method of Separation”.
PHYSICAL PROPERTIES:—Transparent and reddish brown in color, oily in
consistency and has a characteristic tea like odor, heavier than water,
freely soluble in benzol, ether, alcohol and acetone, but insoluble in
petroleum ether and water.
This resin constitutes about eighteen percent of the total ester resins.
By qualitative tests it was shown that the acids contained only carbon,
hydrogen and oxygen. Combustions made on the iron acids gave the
following results.
Wt. of boat 2.6950 2.6950
Wt. of boat and substance 2.8470 2.8495
Wt. of substance .1520 .1545
KOH bulb 50.9620 51.0805
Bulb and CO2 51.3370 51.4610
Wt. of CO2 .3750 .3805
Carbon equivalent .1023 .10376
Sulphuric acid tube 76.2448 76.3450
Tube and water 76.3400 76.4453
Wt. of water .0952 .1003
Hydrogen equiv. .0106 .01114
Percent Carbon 67.3% 67.2%
Percent hydrogen 7.0% 7.2%
Percent Oxygen 25.7% 25.6%
An analysis of the iron salt obtained by precipitation from the
potassium soap gave the following data.
Wt. of substance used .2955 .3387
Wt. of FeSO4 .0445 .0509
Ferric equiv. .03208 .03676
Percent Iron 10.85% 10.85%
The following method was used in making the above analysis. The weighed
material was ignited in a platinum crucible by gently heating until the
combustible gases formed were given off. The crucible was then strongly
heated until the carbonaceous material was completely burned off. The
residue was weighed and the percentage of iron determined.
Expressed as the ACID NUMBER, or the number of milligrams of KOH
required to neutralize the free acids in one gram of the substance,
the following data was obtained.
Ferric equivalent .03208 .03676
Fe expressed as KOH equiv. .0965 .1107
Wt. of material used .2955 .3387
Mg. of KOH per gram 326.6 326.7
Acid number 326.6 326.7
The following gives the ACID NUMBER obtained by direct titration of the
Iron acid. The method is the same as that used in getting the titration
value of the Barium acid.
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