The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association — John Shaqi
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
The specific gravities of acids and alkalis in solution are made use of
in works, etc., as a means of ascertaining their strengths and
commercial values. Tables have been carefully constructed, such that
for every degree of specific gravity a corresponding percentage strength
of acidity and alkalinity may be looked up. The best tables for this
purpose are given in Lunge and Hurter's _Alkali-Makers' Pocket-Book_,
but for ordinary purposes of calculation in the works or factory, a
convenient relationship exists in the case of hydrochloric acid between
specific gravity and percentage of real acid, such that specific gravity
as indicated by Twaddell's hydrometer directly represents percentage of
real acid in any sample of hydrochloric acid.
The point at which neutralisation of an acid by alkali or _vice versa_
just takes place is ascertained very accurately by the use of certain
sensitive colours. At first litmus and cochineal tinctures were used,
but in testing crude alkalis containing alumina and iron, it was found
that lakes were formed with these colours, and they become precipitated
in the solution, and so no longer sensitive. The chemist was then
obliged to resort to certain sensitive coal-tar colours, which did not,
as the dyer and printer knew, form lakes with alumina and iron, such as
methyl orange, fluorescein, Congo red, phenolphthalein, and so forth.
For determining the alkalimetric strength of commercial sodas, a known
weight of the sample is dissolved in water, and a few drops of a
solution of methyl orange are added, which colour the solution yellow or
orange. Into this solution is then run, from a burette or graduated
tube, a standard solution of an acid, that is, a solution prepared by
dissolving a known weight of an acid, say hydrochloric acid, in a known
volume of water. The acid is run in gradually until the yellow colour
changes to pink, at which point the volume of acid used is noted.
Knowing the weight of acid contained in this volume of standard acid,
and having regard to the law of equivalence mentioned above, it is an
easy matter to calculate the amount of alkali equivalent to the acid
used, and from this the alkali contained in the sample.
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