The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
_Sulphuric Acid._--The first process for manufacturing sulphuric acid or
vitriol was by placing some burning sulphur in a closed vessel
containing some water. The water absorbed the acid formed by the burning
sulphur. It was next discovered that by mixing with the sulphur some
nitre, much more sulphuric acid could be produced per given quantity of
brimstone. At first large glass carboys were used, but in 1746 the
carboys were replaced by chambers of lead containing water at the
bottom, and in these lead chambers the mixture of sulphur and nitre was
burnt on iron trays. Next, although gradually, the plant was divided
into two portions--a furnace for burning the sulphur, and a chamber for
receiving the vapours. The system was thus developed into the one
followed at the present time. The sulphur, or, in most cases, cupreous
iron pyrites (a combination of iron and copper with sulphur), is burned
in specially constructed kilns or furnaces, and the hot gases,
consisting essentially of sulphur dioxide with the excess of air, pass
through flues in which are placed cast-iron "nitre pots" containing a
mixture of nitre (sodium nitrate) and vitriol. The gases thus become
mixed with nitrous fumes or gaseous oxides of nitrogen, and, after
cooling, are ready for mixing with steam or water spray in the lead
chambers in which the vitriol is produced. These oxides of nitrogen
enable the formation of sulphuric acid to take place more quickly by
playing the part of oxygen-carriers. Sulphuric acid is formed by the
union of oxygen with sulphur dioxide and water; the oxides of nitrogen
combine with the oxygen of the air present in the chambers, then give up
this oxygen to the sulphur dioxide and water or steam to form sulphuric
acid, again combine with more oxygen, and so on. The exact processes or
reactions are of course much more complicated, but the above represents
what is practically the ultimate result. It is evident that the gases
leaving the last lead chamber in which the formation of vitriol is
effected, must still contain nitrous fumes, and it becomes a matter of
importance to recover them, so that they can be used over again. To
effect this object, use is made of the solubility of nitrous fumes in
strong vitriol. The gases from the last lead chamber of the series are
passed through what is called a Gay-Lussac tower (the process was
invented by the eminent French chemist Gay-Lussac), which is a tower
made of lead, supported by a wooden framework, and filled with coke or
special stoneware packing, over which strong vitriol is caused to flow.
The vitriol dissolves the nitrogen oxides, and so-called "nitrous
vitriol" flows out at the base of the tower. The recovery of the
nitrogen compounds from the nitrous vitriol is effected in Glover towers
(the invention of John Glover of Newcastle), which also serve to
concentrate to some extent the weak acid produced in the lead chambers,
and to cool the hot gases from the sulphur burners or pyrites kilns. The
Public-domain text, read in full here on John Shaqi.
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