The Common Rocks and Minerals of MissouriKeller, W. D.
Science
The Common Rocks and Minerals of Missouri
Keller, W. D.
Mineralogy -- Missouri; Petrology -- Missouri
The shales of Missouri were formed from deposits of mud that settled out
in sea water which in the past covered this state. Fossil remains of
sea-living organisms which are preserved in the shale give evidence of
the marine conditions once existent here. Like the muds that are
accumulating along the Atlantic coast and in the Gulf of Mexico, where
the Mississippi River is discharging its load of silt and clay, so did
mud form layers on the bottom of geologically ancient interior seas. In
some cases sand was later washed in and covered the mud; in other cases
limestone-forming material (like off the coast of Florida today) was
deposited on top of the mud. The weight of the overlying beds and the
slow movement which raised the sea bottom up to land squeezed out the
excess water, compressed and compacted the muds into thin layers, and
brought about the shale rock which is exposed to us today.
[Illustration: Soft, easily eroded bed of shale between two more
resistant beds of limestone near Columbia.]
Black muds, rich in humus and other organic material, formed black
shales; red and yellow clays colored by red and yellow iron oxides (iron
rusts) formed red and yellow shales; and sandy muds were compacted into
gritty, sandy shales. All of them were derived from eroding land and
soils just as today our eroding soils contribute to the formation of
more shale now in the long, slow process of formation.
The chemical composition of an average shale is not simple, as is shown
by the subjoined composite analyses of sedimentary rocks taken from U.
S. Geological Survey Professional Paper No. 127.
78 shales 253 sandstones 345 limestones
SiO₂ 58.11 78.31 5.19
Al₃O₂ 15.40 4.76 .81
Fe₂O₃ 4.02 1.08 .54
FeO 2.45 .30
MnO 2.44 1.16 7.89
CaO 3.10 5.50 42.57
Na₃O 1.30 .45 .05
K₂O 3.24 1.32 .33
H₂O+ 3.66 1.32 .56
H₂O- 1.33 .31 .21
CO₂ 2.63 5.04 41.54
TiO₃ .65 .25 .06
P₃O₅ .17 .08 .04
SO₃ .65 .07 .05
Organic carbon .80 — —
(100.) (100.) approx. (100.)
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