The Common Rocks and Minerals of MissouriKeller, W. D.
Science
The Common Rocks and Minerals of Missouri
Keller, W. D.
Mineralogy -- Missouri; Petrology -- Missouri
Many persons upon learning that average shale, and even “clay dirt,” may
contain 15% alumina, Al₂O₃ (equivalent to almost 8% metallic aluminum),
become thoughtlessly and erroneously enthusiastic about aluminum ore
possibilities on their farms or properties. The aluminum is there all
right, but it is so securely combined with silica and other elements
that the cost of extraction is now greater than the price of aluminum
obtained from less abundant ores. Until chemists find a method of
extraction of the metal from ordinary clay or shale that can be carried
out at considerably less expense than is now possible, the vast
quantities of clay and shale on the earth’s surface must be considered a
distant reserve of a prohibitively high cost aluminum.
Missouri possesses a little bauxitic clay in the southeastern part of
the state but unfortunately does not contain deposits of high grade
bauxite, the chief ore of aluminum, and so does not contribute to the
aluminum production of the United States (see the discussion under
DIASPORE CLAY). Arkansas is a leading producer of bauxite, but the
geological conditions present in that bauxite locality are so different
from Missouri geology that little hope is held for finding bauxite in
Missouri, except possibly in the extreme southeastern part.
Fire Clay
Fire clay resembles shale in that it is also a clayey rock and becomes
muddy upon wetting and rubbing. It differs from shale at sight in that
it (fire clay) is not laminated like shale, but occurs instead in a
massive structure which is relatively uniform throughout. Fire clay
fractures naturally into blocky or irregular fragments ranging in size
from boulders to rough flakes, whereas shale weathers into layered,
platy chips.
Shales are commonly buff, yellow, reddish, greenish, or brown in
addition to gray in color, whereas good useable fire clay predominates
in white, cream, and gray to almost black (if much organic matter is
contained in it). Shale is ordinarily gritty with hard sand particles,
but most good Missouri fire clay contains only a small amount of sand.
Of course, fire clay may grade into sandstone through a sandy clay
phase, but this part would not be confused with a layered, gritty shale.
The really determining characteristic of fire clay is its resistance to
melting under high temperature. The most positive test for this property
is to heat the fire clay to a white heat in comparison with standard
preparations (Pyrometric Test Cones) whose fusion temperatures are
known. Most of Missouri fire clay will withstand a clean oxidizing heat
of over 3000° Fahrenheit without melting.
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