The Common Rocks and Minerals of MissouriKeller, W. D.
Science
The Common Rocks and Minerals of Missouri
Keller, W. D.
Mineralogy -- Missouri; Petrology -- Missouri
Pure limestone is composed of 100% calcium carbonate (calcite mineral),
whereas pure dolomite contains 54.35% calcium carbonate and 45.65%
magnesium carbonate (dolomite mineral). Magnesium carbonate has slightly
higher acid-neutralizing properties than calcium carbonate, weight for
weight, and because analyses of limestone to be used for soil sweetening
and agricultural fertilizer purposes are commonly reported in calcium
carbonate equivalents, a dolomite or dolomitic limestone may be reported
over 100% calcium carbonate equivalent. Unless one understands the full
meaning of the report he may be bewildered by a statement of the value
over 100%.
The calcium and magnesium which form limestone (or dolomitic limestone)
in the ocean are carried there in solution by the streams which drain
the land. Rain water percolating through the ground and rocks becomes
slightly acidified with carbon dioxide (like the carbonated water in
beverages) and dissolves the calcium and magnesium from primary igneous
rocks like gabbro and basalt which are weathering, or from preexisting
limestones which primitively were derived from igneous rocks. This
calcium and magnesium in solution are responsible for the hardness of
the water. In fact, the hard water in Missouri springs, wells, and
streams is hard because it contains either or both calcium (“lime”) and
magnesium in solution.
This soluble calcium and magnesium flows on in the stream to the ocean
because of its combination with the dissolved carbon dioxide. In the
shallow parts of the ocean, as on the continental shelves where the
water is less than 600 feet deep, the limestone is deposited in layers
just like the white lime layer deposits on the bottom of the teakettle
in which hard water has been boiled. Chemical processes, temperature
changes, evaporation of the ocean water, and organisms are responsible
for most of the limestone deposition. Extensive limestone deposition is
taking place today off the coast of Florida and around the tropical
islands of the southern Pacific.
The uses of limestone are numerous. It is an excellent building stone in
either the rough, sawn, or dressed state. It is used for rubble stone,
rip-rap, railroad ballast, crushed gravel, and aggregate in concrete. It
is one of the raw materials of Portland cement. Quicklime and hydrated
lime are prepared from limestone which has been heated to drive off the
chemically combined carbon dioxide.
Limestone is added as a fluxing material in metallurgical processes. It
is the lowest priced source of alkali in chemical industry. Pulverized
limestone may be used as a filler in paints, putty, paper, or rubber;
and rock wool is made by melting and blowing a limestone having a
suitable chemical composition. Two formations develop a “spongy”
appearance (“sponge rock” or “sponge limestone”) upon weathering and are
utilized abundantly in the eastern part of the state for rock gardens
and for ornamental and decorative stone.
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