_Force of Chemical Affinity._
70. Let us now consider the mutual forces between atoms. These may be
characterized as even stronger than the forces between molecules, but
as disappearing still more rapidly when the distance is increased. Let
us, for instance, take carbon and oxygen--two substances which are
ready to combine together to form carbonic acid, whenever they have a
suitable opportunity. In this case, each atom of carbon will unite with
two of oxygen, and the result will be something quite different from
either. Yet under ordinary circumstances carbon, or its representative,
coal, will remain unchanged in the presence of oxygen, or of
atmospheric air containing oxygen. There will be no tendency to combine
together, because although the particles of the oxygen would appear to
be in immediate contact with those of the carbon, yet the nearness is
not sufficient to permit of chemical affinity acting with advantage.
When, however, the nearness becomes sufficient, then chemical affinity
begins to operate. We have, in fact, the familiar act of combustion,
and, as its consequence, the chemical union of the carbon or coal with
the oxygen of the air, carbonic acid being the result. Here, then, we
have a very powerful force acting only at a very small distance, which
we name _chemical affinity_, inasmuch as it represents the attraction
exerted between atoms of different bodies in contradistinction to
cohesion, which denotes the attraction between molecules of the same
body.
71. If we regard gravitation as the representative of forces that act
or appear to act, at a distance, we may regard cohesion and chemical
affinity as the representatives of those forces which, although very
powerful, only act or appear to act through a very small interval of
distance.
A little reflection will show us how inconvenient it would be if
gravitation diminished very rapidly with the distance; for then
even supposing that the bond which retains us to the earth were to
hold good, that which retains the moon to the earth might vanish
entirely, as well as that which retains the earth to the sun, and the
consequences would be far from pleasant. Reflection will also show
us how inconvenient it would be if chemical affinity existed at all
distances; if coal, for instance, were to combine with oxygen without
the application of heat, it would greatly alter the value of this fuel
to mankind, and would materially check the progress of human industry.
_Remarks on Molecular and Atomic Forces._
72. Now, it is important to remember that we must treat cohesion and
chemical affinity exactly in the same way as gravity has been treated;
and just as we have energy of position with respect to gravity, so
may we have as truly a species of energy of position with respect to
cohesion and chemical affinity. Let us begin with cohesion.
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