73. We have hitherto regarded heat as a peculiar motion of the
molecules of matter, without any reference to the force which actuates
these molecules. But it is a well-known fact that bodies in general
expand when heated, so that, in virtue of this expansion, the molecules
of a body are driven violently apart against the force of cohesion.
Work has in truth been done against this force, just as truly as, when
a kilogramme is raised from the earth, work is done against the force
of gravity. When a substance is heated, we may, therefore, suppose that
the heat has a twofold office to perform, part of it going to increase
the actual motions of the molecules, and part of it to separate these
molecules from one another against the force of cohesion. Thus, if I
swing round horizontally a weight (attached to my hand by an elastic
thread of india-rubber), my energy will be spent in two ways--first
of all, it will be spent in communicating a velocity to the weight;
and, secondly, in stretching the india-rubber string, by means of the
centrifugal tendency of the weight. Work will be done against the
elastic force of the string, as well as spent in increasing the motion
of the weight.
Now, something of this kind may be taking place when a body is heated,
for we may very well suppose heat to consist of a vertical or circular
motion, the tendency of which would be to drive the particles asunder
against the force of cohesion. Part, therefore, of the energy of heat
will be spent in augmenting the motion, and part in driving asunder the
particles. We may, however, suppose that, in ordinary cases, the great
proportion of the energy of heat goes towards increasing the molecular
motion, rather than in doing work against the force of cohesion.
74 In certain cases, however, it is probable that the greater part
of the heat applied is spent in doing work against molecular forces,
instead of increasing the motions of molecules.
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