Thus, when a solid melts, or when a liquid is rendered gaseous, a
considerable amount of heat is spent in the process, which does not
become sensible, that is to say, does not affect the thermometer. Thus,
in order to melt a kilogramme of ice, heat is required sufficient to
raise a kilogramme of water through 80° C., and yet, when melted, the
water is no warmer than the ice. We express this fact by saying that
the latent heat of water is 80. Again, if a kilogramme of water at
100° be converted entirely into steam, as much heat is required as
would raise the water through 537° C., or 537 kilogrammes of water
through one degree; but yet the steam is no hotter than the water, and
we express this fact by saying that the latent heat of steam is 537.
Now, in both of these instances it is at least extremely probable that
a large portion of the heat is spent in doing work against the force
of cohesion; and, more especially, when a fluid is converted into a
gas, we know that the molecules are in that process separated so far
from one another as to lose entirely any trace of mutual force. We may,
therefore, conclude that although in most cases the greater portion of
the heat applied to a body is spent in increasing its molecular motion,
and only a small part in doing work against cohesion, yet when a solid
melts, or a liquid vaporizes, a large portion of the heat required
is not improbably spent in doing work against molecular forces. But
the energy, though spent, is not lost, for when the liquid again
freezes, or when the vapour again condenses, this energy is once more
transformed into the shape of sensible heat, just as when a stone is
dropped from the top of a house, its energy of position is transformed
once more into actual energy.
75. A single instance will suffice to give our readers a notion of
the strength of molecular forces. If a bar of wrought iron, whose
temperature is 10° C. above that of the surrounding medium, be tightly
secured at its extremities, it will draw these together with a force of
at least one ton for each square inch of section. In some cases where
a building has shown signs of bulging outwards, iron bars have been
placed across it, and secured while in a heated state to the walls.
On cooling, the iron contracted with great force, and the walls were
thereby pulled together.
76. We are next brought to consider atomic forces, or those which lead
to chemical union, and now let us see how these are influenced by heat.
We have seen that heat causes a separation between the molecules of a
body, that is to say, it increases the distance between two contiguous
molecules, but we must not suppose that, meanwhile, the molecules
themselves are left unaltered.
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