The Daguerreian Journal, Vol. I, No. 8, March 1, 1851 — John Shaqi
The Daguerreian Journal, Vol. I, No. 8, March 1, 1851Various
Science
The Daguerreian Journal, Vol. I, No. 8, March 1, 1851
Various
Daguerreotype; Photography -- Periodicals
The second specimen had the appearance of compact oxide of iron,
containing here and there milk-white quartz; it was throughout impregnated
with chloride of silver, which occasionally appeared in the form of very
small brilliant crystals. To analyze this mineral, 10 grammes were first
treated with ammonia, and heat to dissolve the chloride of silver, and
afterwards by boiling hydrochloric acid to dissolve the oxide of iron;
this acid also dissolved a certain portion of lead, which probably was
in the state of phosphate. The quartzose residue weighed 32.6 grammes:
it contained 0.17 gramme of silver, which must have been in the metallic
state: the ammoniacal solution gave by boiling and saturation with nitric
acid, 1.84 gramme of chloride of silver, which, supposing it to be pure,
contained 1.40 gramme of silver, which, added to 0.17 gramme remaining
in the quartz, gives a total of 1.57 gramme; a result which differed so
very little from that obtained by essaying, as to prove the absence of
bromide of silver, and that this was the case was confirmed by additional
experiments.
After this a third specimen was received from Huelgoeth; it was very
small, but as rich as the foregoing, and in it there were distinguishable,
besides granular cubic crystals of chloride of silver, other grains of an
olive-green color, which had exactly the same appearance as the bromide
had. Plateros and the following experiments proved the presence of the
substance.
Five grammes of the pulverized mineral were boiled in a solution of oxalic
acid, until the oxide of iron was perfectly dissolved: the residue weighed
about a gramme, and it evidently contained a mixture of canary-yellow and
white grains. It was digested in hot solution of ammonia until all the
yellow powder disappeared; it required a large quantity of the alkali
for this purpose, which would not have been the case to dissolve pure
chloride. The solution was gradually saturated with nitric acid, and it
was observed that the successive deposits formed had an evident yellow
tint, but gradually diminishing in intensity, except the last, which were
white. The yellow deposits were collected and examined in the following
manner:--A portion was treated with chlorine and æther; the æther became
of a yellow color. Another portion was dissolved in ammonia, hydrosulphate
of ammonia was added to the solution, and the black precipitate formed was
separated, and was found to be pure sulphuret of silver. The liquor was
concentrated by exposure to the air, and filtered to separate the sulphur
which was deposited; a little potash was then added, and it was evaporated
to dryness; acetic acid was added to saturate the excess of potash, and it
was again dried.
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