The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student — John Shaqi
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
(1) =Zinc Chloride.=--When cotton or other form of cellulose is heated
with a strong solution, 40 to 50 per cent., it slowly dissolves to a
syrupy liquid. On diluting this liquid with water the cellulose is
thrown down in a gelatinous form, but more or less hydrated, and
containing some zinc oxide, 18 to 25 per cent., in combination.
(2) =Zinc Chloride and Hydrochloric Acid.=--When zinc chloride is
dissolved in hydrochloric acid a liquid is obtained which dissolves
cellulose; on dilution the cellulose is re-precipitated in a hydrated
form. It is worth noting that the solution is not a stable one: on
keeping, the cellulose changes its character and undergoes hydrolysis to
a greater or less extent.
(3) =Ammoniacal Copper.=--When ammonia is added to a solution of copper
sulphate, there is formed at first a pale blue precipitate of copper
hydroxide, which on adding excess of ammonia dissolves to a deep blue
solution--a reaction highly characteristic of copper. The ammoniacal
copper solution thus prepared has, as was first observed by John Mercer,
the property of dissolving cellulose fairly rapidly, even in the cold.
If instead of preparing the ammoniacal copper solution in the manner
indicated above, which results in its containing a neutral ammonium
salt, the copper hydroxide be prepared separately and then dissolved in
ammonia a solution is obtained which is stronger in its action.
The cupra-ammonium solutions of cellulose are by no means stable but
change on keeping. When freshly prepared, the cellulose may be
precipitated from them almost unchanged by the addition of such bodies
as alcohol, sugar and solutions of neutral alkaline salts. On keeping
the cellulose undergoes more or less hydrolysis or even oxidation, for
it has been observed that oxycellulose is formed on prolonged digestion
of cellulose with cupra-ammonium solutions, while there is formed a
fairly large proportion of a nitrite.
On adding lead acetate to the cupra-ammonium solution of cellulose, a
compound of lead oxide and cellulose of somewhat variable composition is
precipitated. It is of interest also to note that on adding metallic
zinc to the cupra-ammonium solution the copper is thrown out and a
solution containing zinc is obtained.
This action of cupra-ammonium solutions on cellulose has been made the
basis for the production of the "Willesden" waterproof cloths. Cotton
cloths or paper are passed through these solutions of various degrees of
strength according to requirements, they are then passed through rollers
which causes the surface to become more compact. There is formed on the
surface of the goods a deposit of a gelatinous nature which makes the
surface more compact, and the fabric becomes waterproof in character
while the copper imparts to them a green colour and acts as a
preservative. The "Willesden" fabrics have been found very useful for a
variety of purposes.
CHAPTER II.
SCOURING AND BLEACHING OF COTTON.
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