Instead of using the gas, the sulphur dioxide may be applied in the
form of a solution in water. The goods are then simply steeped for
some hours in a solution of the gas in water until they are bleached,
then they are rinsed in water and dried. In this method it is
important that the solution of the gas be freshly made, otherwise it
is liable to contain but little sulphurous acid, and plenty of
sulphuric acid which has no bleaching properties, but, on the other
hand, is liable to lead to damage of the goods if it be not washed out
afterwards.
A better method of utilising the bleaching action of sulphur in a
liquid form is to prepare a bath of bisulphite of soda, and acidify it
with hydrochloric acid, then to enter the wool, stirring well for some
time, and allowing it to steep for some hours, next to expose to the
air for a while, and rinse as before.
It is better to allow the wool to steep for about an hour in a simple
bath of bisulphite, then enter into a weak hydrochloric acid bath for
a few hours. The acid liberates sulphur dioxide in a nascent
condition, which then exerts a more powerful bleaching action than if
it were already free.
Even with liquid bleaching the bleach is not any more perfect than it
is with the gas bleaching; the colour is liable to come back again on
being washed with soap or alkali, although there is a freedom from the
defect of yellow stains being produced.
Goods properly bleached will stand exposure to air for some
considerable time, but those imperfectly bleached exhibit a tendency
to regain their yellow colour on exposure to air. One fault which is
sometimes met with in sulphur bleaching is a want of softness in (p. 034)
the wool, the process seeming to render the fibre harsh.
Washing in a little weak soft soap or in weak soda will remedy this
and restore the suppleness of the wool; at the same time care must be
taken that the alkaline treatment is not too strong, or otherwise the
bleaching effect of the sulphur will be neutralised as pointed out
above.
Public-domain text, read in full here on John Shaqi.
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