#Bleaching Wool by Peroxide of Hydrogen.#--During recent years there has
come into use for bleaching the animal fibres peroxide of hydrogen,
or, as the French call it, oxygenated water. This body is a near
relation to water, being composed of the same two elements, oxygen and
hydrogen; in different proportions in water these elements are
combined in the proportion of 1 part of hydrogen to 8 parts of oxygen,
while in the peroxide the proportions are 1 of hydrogen to 16 of
oxygen. These proportions are by weight, and are expressed by the
chemical formulae for water H_{2}O, and for hydrogen peroxide
H_{2}O_{2}. Water, as is well known, is a very stable body, and
although it can be decomposed, yet it requires some considerable power
to effect it. Now the extra quantity of oxygen which may be considered
to have been introduced into water to convert it into peroxide has
also introduced an element of instability, the extra quantity of
oxygen being ever ready to combine with some other body for which it
has a greater affinity than for the water. This property can be
utilised in the bleaching industry with great advantage, true
bleaching being essentially a process of oxidation. The colouring
matter of the fibre, which has to be destroyed so that the fibre shall
appear white, is best destroyed by oxidation, but the process must not
be carried out too strongly, otherwise the oxidation will not be
confined to the colouring matter, but will extend to the fibre itself
and disintegrate it, with the result that the fibre will become
tendered and be rendered useless.
Peroxide of hydrogen is a weak oxidiser, and therefore, although (p. 035)
strong enough to destroy the colouring matter of the fibre is not
strong enough to decompose the fibre itself. Hydrogen peroxide is sold
as a water-white liquid, without any odour or taste. Its strength is
measured by the quantity of oxygen which is evolved when one volume of
the liquid is treated with potassium permanganate; the most common
strength is 10 volume peroxide, but 30 and 40 volume peroxide is made.
On keeping it loses its oxygen, so that it is always advisable to use
a supply up as quickly as possible.
Public-domain text, read in full here on John Shaqi.
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