The operation of chlorination can be done either in one or two (p. 038)
baths. The choice depends upon circumstances and the judgment of the
dyer. The process by the two-bath method, with subsequent dyeing in
the second or separate bath is (for 100 lb. of wool), as follows. The
first bath contains, for light cloths, yarn, etc., from 3 to 4 lb.
sulphuric acid, 168 deg. Tw., and for heavier cloths and felt, where the
penetration and equalisation of the colour is difficult, from 8 lb. to
10 lb. of acid. Generally speaking, a temperature of 170 deg. to 175
deg. F. is sufficient, although for heavy wool and for wool with poor
dyeing qualities it is well to use the bath at the boil. The treatment
lasts for half an hour, in which time the acid is almost completely
absorbed.
The second bath contains a clear solution of 10 lb. bleaching powder,
which solution is prepared as follows. Dry bleaching powder of the
best quality is stirred in a wooden vat with 70 gallons of water, the
mass is allowed to stand, the clear, supernatant liquor is run into
the vat and the sediment stirred up and again allowed to settle, the
clear liquor being run off as before, and 5 gallons more water is run
in. The clear liquors of these three treatments are then mixed
together to form the chloring bath. Special care should be taken that
no undissolved particles of the bleaching powder should be left in,
for if these settle on the wool they result in too great a development
of chlorine, which injures the wool.
The goods after being in the acid bath are entered in this chlorine
bath at a temperature of 70 deg. F., which is then raised to the boil. If
the acid bath has been strong, or been used at the boil, it is perhaps
best to rinse the goods before entering into the chlorine bath. The
hypochlorous acid disappears so completely from this bath that it may
at once be used as the dye-bath, for which purpose it is only necessary
to lift the goods, add the required amount of dye-stuff, re-enter the
goods and work until the bath is exhausted, which generally happens when
acid dyes are used. If a separate dye-bath be preferred, this is (p. 039)
made and used as is ordinarily done.
To perform all the operations in one bath the acid bath is made with
from 3 to 4 lb. sulphuric acid, and the wool is treated therein for
thirty minutes at 170 deg. F., until all the acid has been absorbed. Then
the bath is allowed to cool down to 70 deg. or 80 deg. F., the clear
bleaching powder solution is added, the goods are re-entered, and the
bath is heated to the boil. When all the chlorine has disappeared add the
dye-stuff, and dye as directed above.
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