#Bleaching with Peroxide of Soda.#--Peroxide of soda has come to the
front of late for bleaching wool. With it a stronger bleaching bath
can be made, while the product itself is more stable than peroxide of
hydrogen, only it is needful to keep it in tightly closed metal
vessels, free from any possibility of coming in contact with water or
organic matter of any kind, or accidents may happen. In order to
bleach 100 lb. of wool, a bath of water is prepared, and to this is
added 6 lb. of sulphuric acid and then slowly 4 lb. of peroxide of
sodium in small quantities at a time. Make the bath slightly alkaline
by adding ammonia. Heat the bath to 150 deg. F., enter the wool and allow
to remain five to six hours, then rinse well and dry. If the (p. 037)
colour does not come out sufficiently white repeat the process.
THE CHLORINATION OF WOOL.
The employment of chlorine in wool dyeing and wool printing has of
late years received an impetus in directions previously little thought
of. The addition of a little chlorine to the decoction of logwood has
been recommended as increasing the dyeing power of the wool. Treating
the wool with chlorine has a material influence in increasing its
capacity for taking dye-stuffs, and although but little attention has
been paid to this circumstance by wool dyers, yet among wool printers
it has come largely into use, and enables them to produce fuller and
faster shades than would otherwise be possible.
The method involves the treatment of the wool first with an acid, then
with a solution of a hypochlorite. The staple becomes soft and supple
and assumes a silky character; in dyeing it shows a greater affinity
for the dyes than it did previously. Although not deteriorated in
strength, it almost entirely loses its felting properties. On account
of this feature the process cannot be adopted for wool which has to be
fulled, but it is of service where felting of the goods is to be
avoided, for worsteds, underwear, woollen and half woollen hosiery,
etc., in which the felting property that occurs on washing is rather
objectionable.
By the chloring of the wool the intensity of the shade dyed is
increased to such a degree that when dyeing with Acid black, Naphthol
black, Naphthol green, Nigrosine, Fast blue, Water blue, and some
others dyed in an acid bath, but little more than half the dye used on
unchlored wool is required, while with Induline, more even and intense
shades are obtained than is otherwise possible.
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