The Elements of Blowpipe AnalysisGetman, Frederick Hutton
Science
The Elements of Blowpipe Analysis
Getman, Frederick Hutton
Blowpipe
~Stephanite~, Ag_{5}S_{4}Sb, Ag . 68.5, Sb . 15.3, S . 16.2.--H = 2.0-2.5,
G = 6.2-6.3. Color, iron-black to blackish gray. Lustre, metallic. Very
brittle and fragile. In an ignition tube it decrepitates, fuses, and
finally yields a slight sublimate of antimony trisulphide. Before the
Bp. on Ch. gives a coating of antimonious oxide. Before the Bp. on Ch.
with Na_{2}CO_{3} a globule of metallic silver is obtained. The mineral
frequently contains copper and iron.
~Kerargyrite~, AgCl, Ag . 75.3, Cl . 24.7.--H = 1.0-1.5, G = 5.52. Color,
white, gray, yellowish, greenish to blue. Lustre, resinous, adamantine.
Soft like wax. Fuses easily in a candle-flame. Before the Bp. on Ch. it
is readily reduced to metallic silver.
ORES OF TIN
~Cassiterite~, SnO_{2}, Sn . 79, O . 21.--
H = 6.0-7.0, G = 6.8-7.0.
Color, brown, black. Lustre, adamantine, brilliant. Occurs crystallized
in square prisms. Reëntrant angles characteristic. Before the Bp. on Ch.
with Na_{2}CO_{3} and KCN reduced to a metallic globule of tin. In the
borax bead gives characteristic reaction.
~Stannite~, 2 Cu_{2}S . SnS_{2} + 2 (FeS . ZnS) Sn . S_{2}.--H = 4.0, G =
4.3-4.5. Color, steel-gray to iron-black. Lustre, metallic. Occurs
usually massive and disseminated. Heated in an ignition tube it yields
sulphur dioxide. Before the Bp. on Ch. it emits sulphur dioxide and
becomes covered with oxide of tin. Before the Bp. on Ch. with
Na_{2}CO_{3} and KCN it gives an impure globule of copper. A very
difficult mineral to determine.
ORES OF ZINC
~Calamine~, H_{2}Zn_{2}O_{5}Si, SiO_{2} . 25.0, ZnO . 67.5, H_{2}O .
7.5.--H = 4.5-5.0, G = 3.4-3.5. Color, white, gray, bluish, or brown.
Lustre, vitreous. Brittle. In an ignition tube yields water when heated
and becomes milky white. Before the Bp. on Ch. practically infusible.
With Co(NO_{3})_{2} it assumes a green color which passes into a fine
blue when the heat is increased.
~Smithsonite~,
Zn . CO_{3}, ZnO . 64.8, CO_{2} . 35.2.--
H = 5, G = 4.30-4.45. Color, gray, yellow, brown, and green. Lustre,
vitreous, pearly. Heated in an ignition tube CO_{2} is evolved, residue
appearing white. It often contains impurities of Cd, Pb, Fe, Mn, Ca, and
Mg. When these are present the residue in the ignition tube becomes dark
on cooling. Before the Bp. on Ch. with Na_{2}CO_{3} and exposed to the
R. F. it is decomposed. It gives the characteristic reaction for zinc
with Co(NO_{3})_{2}.
~Zincite~, ZnO, Zn . 80.3, O . 19.7--
H = 4.0-4.5, G = 5.43-5.70.
Color, blood-red. Lustre, brilliant, subadamantine. Before the Bp. on
Ch. infusible. Before the Bp. on Ch. with Na_{2}CO_{3} gives coating of
zinc oxide. Gives characteristic reaction with Co(NO_{3})_{2}. It
frequently contains a small quantity of Mn_{2}O_{3}, which may be
detected in the borax bead.
~Sphalerite~, ZnS, Zn . 67, S . 33.--
H = 3.5-4.0, G = 3.9-4.1.
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