The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution. — John Shaqi
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
The experiment is particularly instructive, in the first place,
because it illustrates with a gas, subject to the laws of gases, why
and how osmosis takes place through a semipermeable membrane—namely
as a result of the solubility of the diffusing substance in the
membrane, and through the flow of the diffusing substance [p026]
from higher to lower concentrations. In the second place, while
the increase in total pressure in the inner chamber undoubtedly is
‹brought about› by the ‹osmosis› of ‹hydrogen› into the chamber,
the excess pressure when equilibrium has been reached, necessarily
measures accurately the partial pressure of the ‹nitrogen›. In other
words, the semipermeable membrane is merely a means or ‹device for
measuring› the partial pressure of the nitrogen—the membrane is not
the ‹cause› of the pressure; the latter is a definite one, whether we
know what it is or not, and the osmosis of the hydrogen through the
palladium merely gives us a means of ascertaining it. Similarly, it
would be wrong to consider that the osmotic pressure of a solution
is caused, or brought about, by the flow of the solvent through a
semipermeable membrane (osmosis); the latter simply is a ‹device›
which enables us to recognize and ‹measure› the pressure that exists
in the solution, both in the presence and the absence of such a
membrane.
We may consider, then, that the osmosis, or migration of the solvent
through a semipermeable membrane into a solution, is the result of
the reduced concentration (or ‹partial pressure›) of the solvent in
the solution, resulting from the presence of the solute.
Inasmuch as the ‹effect› of the ‹solute› on the solvent can be
overcome by a ‹pressure› on the surface of the solution, one is led
to the conclusion that the solute acts by exerting, in turn, ‹a force
or pressure› against the surfaces of the solvent, in the directions
opposite to the hydrostatic pressure required to overcome it. The
significant identity of the value of this pressure, as thus measured,
with the gas pressure that would be exerted by a gas of the same
number of molecules, in the same volume and at the same temperature,
leads us to the last of the three questions which have been raised,
namely, the question concerning the theory of the intimate relations
between gas and osmotic pressures (p. 21).
«The Kinetic Theory and Osmotic Pressure.»—For an answer to this
fundamentally interesting theoretical question one turns, naturally,
to the kinetic theory, which, in the hands of Clausius, Joule,
van der Waals and others, has given us a very satisfactory and
essentially complete theoretical interpretation of the behavior of
gases, and of the liquids to which they may be compressed.
Public-domain text, read in full here on John Shaqi.
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