The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
The laws of gases, it is known, are in accord with the two simple
assumptions of the kinetic theory. The first assumption is that
[p027] gases consist of ultimate discrete particles (molecules),
which move in all directions through the space filled by the gas and,
at ordinary pressures, are so far apart, that the forces of molecular
attraction between them are negligible; the ‹pressure› of the gas
is simply the net result of the impacts of these flying particles
upon the walls of the containing vessel. The second assumption of
the kinetic theory is that ‹temperature› is a function of the mean
kinetic energy of the moving molecules, and that the molecules of
gases of the same temperature have the same mean kinetic energy. The
kinetic energy of particles is a function of their mass ‹m› and their
velocity ‹u› (K.E. = ½ ‹m› ‹u›^2). When a gas is heated, the kinetic
energy of its molecules is increased, and, since their masses remain
unchanged, their velocity must increase. As a result, the number
and the force of their impacts against the walls of a given space
increase, and thus the pressure is increased.
We may ask, whether this theory cannot be used to explain the
connection between osmotic and gaseous pressure. If temperature
is a function of the kinetic energy of the molecules of which
a substance consists,—and the whole behavior of gases confirms
such a conception,—then one must conclude, that the mean kinetic
energy of molecules, at a given temperature, must always be the
same, irrespective of whether they are present in gaseous, or
liquid, or solid form, or even in solution.[39] The tendency of the
molecules to move, resulting from the kinetic energy inherent at a
given temperature, may be largely balanced (liquids), or overcome
(solids), by molecular attractions of surrounding particles, but
such conditions are altogether in harmony with the conception of
a definite mean molecular kinetic energy, persisting at a given
temperature, irrespective of the physical surroundings of the
molecule. According to the kinetic theory, then, when we have a
dilute solution, say of alcohol in water, the molecules of alcohol,
at a given temperature, would have a given mean kinetic energy,
[p028] and would be tending to move in all directions with a
mass[40] and velocity, the same as if the alcohol were present as a
gas or vapor at the same temperature. If the solution is sufficiently
dilute, the dissolved alcohol molecules are sufficiently far apart,
for average time, to make the molecular attractions between them
negligible, just as is assumed for gases. As far as the alcohol
(solute) molecules alone are concerned, they may, evidently, be
assumed to be present in the solution, in the same condition, as to
number, mean kinetic energy and mean velocity, as they would be in
alcohol vapor of the same concentration and temperature. We may ask,
now, whether the osmotic pressure of the solution may not result from
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