The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
To recognize, in a substance, the presence of any element or
compound, one must know its characteristic reactions, which will make
it possible to distinguish it from all other elements or compounds.
Further, in order to reach conclusions with the greatest possible
speed, directness, and conclusiveness, it is usually best to carry
out an examination in some systematic way, rather than in a haphazard
and irregular fashion. We distinguish, accordingly, two parts in
our laboratory work: first, the study of characteristic tests or
‹reactions› of the common elements and such of their compounds as
are of importance in elementary analysis (Part III), and, secondly,
practice in a ‹systematic› method of analysis (Part IV). In the study
of the reactions, the way will be paved for systematic analysis, by
taking the elements in the groups, which form the basis of the system
of analysis employed, and by analyses of mixtures of the elements of
a group immediately after the group has been studied.
Reliable and intelligent analysis is possible only with a clear
knowledge of the chemistry of the reactions used, and the chemistry
of the most important typical reactions will therefore be considered
(in Part II), simultaneously with the laboratory study of the
reactions and of systematic analysis.
The reactions for identifying an element or compound must bring
physical evidence which can be recognized by our senses. The sense
of ‹touch› is scarcely ever appealed to; perhaps the numbness or
paralysis of the sense of touch imparted to the tongue or eyelid by
the alkaloid cocaine and a few modern substitutes for it, and the
tingling sensation produced on the tongue [p005] by aconite and
its preparations, are the most important, but rare, instances of an
appeal to this sense in analytical work. The sense of ‹taste› is also
rarely used, and always with the greatest care to prevent poisonous
effects. Acids and bases, bitter alkaloids, such as strychnine and
brucine, sweet substances, such as cane sugar, glucose, glycerine,
are instances of compounds which affect our sense of taste. In all
these cases the taste is used rather as a confirmative test than as a
conclusive proof of the identity of a suspected substance.
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