There is also a large amount of oil produced in the United States,
mainly in Pennsylvania, which is of a character especially suited to
the production of high grade lubricants by a simple refining method.
With oil of this character the lubricating constituents do not require
distillation to separate them from impurities. The crude petroleum
may be directly reduced by distillation, taking off the three major
fractions, that is, gasoline, kerosene and gas oil, and leaving behind
in the still a very good grade of lubricating oil which, however,
contains paraffine wax. To separate this wax from the lubricating oil,
in which it is dissolved, an ingenious process called cold settling
is resorted to. According to this process, the mixture of lubricating
oil and wax is diluted with gasoline, enough gasoline being employed
to make a very thin liquid, and the mixture is then chilled to a low
temperature. From the chilled mixture the paraffine separates out in
the form of a thick grease which settles to the bottom of the chilling
tank. This grease is subsequently refined to produce the various grades
of petroleum jelly. The lubricating oil diluted with naphtha and
separated from the paraffine or grease as described is subjected to
re-distillation for the separation of the naphtha and forms a base for
the production of a wide variety of high grade lubricants.
Returning to the analogy by which we compared crude petroleum oil to
crude gravel mined from the hillsides, it will be noted as in the
case of the gravel, the various crude petroleums differ in character
considerably, according to their origin, and that the refining process
must be modified to suit the character of the oil.
The analogy may be pursued one step further to explain one of the most
interesting developments of the modern petroleum industry, i. e., the
manufacture of gasoline not naturally contained in crude petroleum.
This process of _manufacturing gasoline_ is called “cracking.”
Let us assume that we desire to obtain from crude gravel, mined from
the ground, a maximum amount of fine gravel. We would first use all of
the fine gravel which was naturally contained in the crude gravel and
then we might pass the remainder of the gravel, which is too large for
our use, through crushing rollers which would crush or crack it, thus
producing an additional quantity of fine gravel. An analogous process
has now been successfully developed for the treatment of petroleum
oils. According to this process, a heavier constituent of the crude
petroleum oil, for example, kerosene or gas oil, may be subjected to
distillation at high temperatures, and under high pressure in special
stills designed for this process, thus securing increased quantities
of gasoline. In this operation a certain proportion of the heavier oil
treated is caused to break down into gasoline. The U. S. Bureau of
Mines estimates that in 1919 some 15% of the country’s total gasoline
production was obtained by this process.
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