The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Substances were not supposed always to be completely deprived of
phlogiston by combustion. Indeed, if the phlogiston were removed
wholly, or nearly so, it was by no means easy to restore it. Thus
the calx of zinc, or of iron, which was regarded as nearly devoid of
phlogiston, is difficult to reduce to the metallic state by ignition
with substances rich in phlogiston, such as coal or charcoal. The
addition of phlogiston alters the appearance of the substance as
regards colour or metallic lustre, and these vary according to the
proportion of phlogiston present.
There existed no very definite idea regarding the appearance or
properties of phlogiston itself. Becher’s name for it was _terra
pinguis_, and it was represented by Becher and by Stahl as a dry
substance of an earthy nature, consisting of very fine particles, which
were capable of being set into violent motion; this idea was derived
partly from the fact that combustion is usually accompanied by flame,
which was supposed to be produced by the motion of the particles of the
body, communicated to it by the phlogiston.
It must not be forgotten that at this time it was perfectly well known
that metals gain weight on calcination. Jean Rey was quite aware of
this, and Boyle relates an experiment to show that tin gains weight
when converted into calx; and it will be remembered that Mayow made
experiments on the ignition of antimony by the aid of a burning-glass,
and rightly conjectured that the substance produced was the same as
that formed by treating it with nitric acid, and subsequent ignition.
Boyle’s view was that calx of tin was a compound of _tin_ and _heat_;
Mayow’s more correct view was that calx of antimony was a compound of
_antimony_ and _fire-air_. But in spite of these well-proved facts,
the adherents of the theory of phlogiston ignored them, and it does
not appear to have occurred to Becher or to Stahl that they were
inconsistent with their theories.
When this difficulty was stated, which was not until a much later
date, a lame explanation of a metaphysical nature, and in itself
contradictory, was all that could be offered. It was that phlogiston
is endowed with the contrary of gravity or weight, _i.e._ levity or
absolute lightness. This means, of course, that it is repelled by the
earth. But if repelled by matter, how comes it that it enters into
combination with matter? For it could not remain united if its property
were to repel and not to attract. Notwithstanding this, however, the
idea satisfied some as to the gain in weight which metals undergo in
changing into calces.
Public-domain text, read in full here on John Shaqi.
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