The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
George Ernest Stahl was born at Anspach in 1660; he studied and
graduated in medicine at Halle, and in 1694 he was appointed second
professor of medicine at that University, where he continued
to teach for twenty-two years. His most important work was his
_Fundamenta chymiae dogmaticae et experimentale_. His theoretical
views are contained in the last part of this work. He there treats
of _zymotechnia_, or fermentation; _halotechnia_, or the production
of salts; and _pyrotechnia_, or the doctrine of combustion. It is
the last of these sections which gives an account of the doctrine of
_phlogiston_.
The fundamental conception of this doctrine is that all combustible
bodies are compounds. During combustion one of these constituents,
common to all, was dissipated and escaped, while the other, sometimes
an acid, sometimes an earthy powder or calx, remained behind. Thus
sulphur and phosphorus, when burnt, give acids; and the metals form
_calces_. Non-combustible substances, such as lime, were imagined to
be _calces_, and it was supposed that if phlogiston were restored
to them, they too would be converted into metals. This combustible
principle was thought to be inherent in all combustible bodies
whatsoever; it corresponds in kind with the “sulphur” of more ancient
writers, but differs from the latter inasmuch as no very precise ideas
were entertained of the identity of the “sulphur” which conferred on
the substances containing it as a constituent, or possessing it as a
property, their power of combustion. It was also made more definite by
Stahl that substances capable of burning or conversion into calces are
compounds containing phlogiston in combination with other substances.
Stahl can hardly be credited with more than the invention of the term
“phlogiston,” and with bringing the subject in a clear and definite
form before his contemporaries. For Stahl wrote in 1720; and we find
Mayow, in 1674, entering into an elaborate argument to prove that
sulphuric acid is not contained in sulphur, but that it is produced
by the union of the sulphur with his fire-air particles. But Stahl
amplified the doctrine which Mayow had controverted, in pointing
out that if such substances as phosphorus, sulphur, or metals are
heated, they burn, and are changed into phosphoric acid, sulphuric
acid, or “calces”; and reciprocally, if phosphoric acid, sulphuric
acid, or a calx such as that of tin or lead, is heated with matter
rich in phlogiston, such as charcoal, pitcoal, sugar, flour, etc.,
phlogiston is restored to the burnt substance, and the original
material, phosphorus, sulphur, tin, or lead, is reproduced. The idea
at once captivated the minds of the chemists of that age, who received
it with approbation, and devised experiments designed to extend the
applications of the theory and to confirm its truth.
Public-domain text, read in full here on John Shaqi.
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