The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
After defining the properties characteristic of air, namely, its
power of supporting combustion, its diminution by one third or one
quarter during the combustion of any substance which does not produce
any fluid resembling air, its insolubility in water, its power of
supporting life, and the fact of its being favourable to the growth
of plants, Scheele demonstrates that air must consist of at least
two elastic fluids. This he proves by exposing it to “liver of
sulphur” (polysulphide of potassium), when six parts out of twenty
were absorbed. He obtained the same result by employing a solution
of sulphur in caustic potash, and also by polysulphide of calcium,
prepared by boiling lime-water with sulphur, and by means of yellow
sulphide of ammonium. Nitric oxide, “the nitrous air which arises
on the dissolution of metals in nitrous acid,” produces a similar
contraction, and so also do oil of turpentine and “drying oils” in
general. Dippel’s animal oil, obtained by distilling bones, and ferrous
hydroxide, produced from “vitriol of iron” and “caustic ley,” or
ferrous sulphate and caustic potash, may also be used as absorbents;
as may also iron filings moistened with water, a solution of iron in
vinegar, and a solution of cuprous chloride. “In none of the foregoing
kinds of air can a candle burn or the smallest spark glow.”
He accounts for these results by the theory that all such absorbents
contain phlogiston, which is attracted by the air, and, combining with
it, diminishes its bulk. The alkalies and lime attract the vitriolic
acid of the sulphides used, and the air attracts the phlogiston. “But
whether the phlogiston which was lost by the substances was still
present in the air left behind in the bottle, or whether the air which
was lost had united and fixed itself with the materials, such as liver
of sulphur, oils, etc., are questions of importance.”[13] The conclusion
that such air, which had received phlogiston and had contracted in
volume, ought to be specifically heavier than common air was, however,
rudely dissipated by experiment. The air must therefore contain two
fluids, one of which does not manifest the least attraction for
phlogiston, while the other is peculiarly disposed to such attraction.
“But where this latter kind of air has gone to, after it has united
with the inflammable substance, is a question which must be decided by
further experiments, and not by conjectures.”[14]
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