The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
To decide this question, Scheele burned in air substances such as
phosphorus, which do not produce by their combustion any kind of “air.”
The result was that the air lost 9 volumes out of an original 30, or
about one-third of its bulk. A flame of hydrogen burning in air caused
it to lose one-fifth of its volume. On burning a candle, some spirits
of wine, or some charcoal, in a confined quantity of air, very little,
if any, diminution of volume was noticed; but on shaking the air with
milk of lime, contraction ensued, but not to the same extent as when
phosphorus was burnt in it. This greatly puzzled Scheele; we now know
that such combustibles are not able to remove all the oxygen, but that
they are extinguished when only a portion of each has entered into
combination. Here, again, however, his memory comes to his help, for he
says, “It is known that one part of aerial acid mixed with ten parts
of ordinary air extinguishes fire; and there are here in addition,
expanded by the heat of the flame and surrounding the latter, the
watery vapours produced by the destruction of those oily substances. It
is these two elastic fluids, separating themselves from such a flame,
which present no small hindrance to the fire which would otherwise burn
much longer, especially since there is here no current of air by means
of which they can be driven away from the flame. When the aerial acid
is separated from this air by milk of lime, then a candle can burn in
it again, though only for a very short time.”[15] Thus the question was
correctly solved. Scheele’s acumen led him at once to make experiments
admirably adapted to discover the true reason; he was not turned aside
by any imaginary difficulties, but went straight to the point. He next
burned sulphur in confined air, and found little alteration of volume,
but on shaking with clear lime-water, absorption took place, and
one-sixth of the air was removed. “The lime-water was not in the least
precipitated in this case, an indication that sulphur gives out no
aerial acid during its combustion, but another substance resembling
air; this is the volatile acid of sulphur, which occupies again the
empty space produced by the union of the inflammable substance with
air.”[16]
The next set of experiments were devised “to prove that ordinary
air, consisting of two kinds of elastic fluids, can be compounded
again, after these have been separated from one another by means of
phlogiston.”
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account