The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
But the origin of the acid in water made from inflammable and
dephlogisticated air was still unexplained. To settle this point
Cavendish added to an explosive mixture of oxygen and hydrogen a tenth
of its volume of nitrogen, and found that the water was much more
strongly acid; and if hydrogen was much in excess, a still greater
amount of nitric acid was produced. After relating these experiments he
proceeds:--
“From what has been said there seems the utmost reason to think that
dephlogisticated air is only water deprived of its phlogiston, and
that inflammable air, as was before said, is either phlogisticated
water or else pure phlogiston, but in all probability the former.” In
a foot-note he gives his reason for the choice, viz. that it requires
a red-heat to cause hydrogen and oxygen to combine, while nitrous air
combines with oxygen at the ordinary temperature; now, if hydrogen
were pure phlogiston, one would expect it to combine more readily than
nitrous gas, which has been shown to be a compound of nitric acid with
phlogiston. It seems inexplicable that dephlogisticated air should
refuse to unite at the ordinary temperature with pure phlogiston, when
it is able to extract it from substances with which it has an affinity.
Hence it is unlikely that hydrogen is phlogiston itself.
And a few paragraphs farther on Cavendish very nearly discards the
phlogistic theory by this statement: “Instead of saying air is
phlogisticated or dephlogisticated by any means, it would be more
strictly just to say, it is deprived of, or receives, an addition of
dephlogisticated air; but as the other expression is convenient, and
can scarcely be considered as improper, I shall still frequently make
use of it in the remainder of this paper.”
And now we come to the consideration of Lavoisier’s new theory, and
its rejection in favour of the old one of phlogiston. It is curious to
follow the reasoning which made such an exceptionally acute thinker as
Cavendish deliberately reject the true explanation. Cavendish first
states his results in Lavoisier’s terms:--
Public-domain text, read in full here on John Shaqi.
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