The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“According to this hypothesis, we must suppose that water consists
of inflammable air united to dephlogisticated air; that nitrous air,
vitriolic acid air (sulphur dioxide), and the phosphoric acid are
also combinations of phlogisticated air, sulphur, and phosphorus with
dephlogisticated air; and that the two former, by a further addition
of the same substance, are reduced to the common nitrous and vitriolic
acids; that the metallic calces consist of the metals themselves united
to the same substance, commonly, however, with a mixture of fixed air;
that on exposing the calces of the perfect metals to a sufficient
heat, all the dephlogisticated air is driven off, and the calces are
restored to their metallic form; but as the calces of the imperfect
metals are vitrified by heat, instead of recovering the metallic
form, it should seem as if all the dephlogisticated air could not be
recovered from them by heat alone. In like manner, according to this
hypothesis, the rationale of the production of dephlogisticated air
from red precipitate is, that during the solution of the quicksilver
in the acid and the subsequent calcination, the acid is decompounded,
and quits part of its dephlogisticated air to the quicksilver, whence
it comes over in the form of nitrous air, and leaves the quicksilver
behind united to dephlogisticated air, which, by a further increase
of heat, is driven off, while the quicksilver resumes its metallic
form. In procuring dephlogisticated air from nitre, the acid is also
decompounded; but with this difference, that it suffers some of its
dephlogisticated air to escape, while it remains united to the alkali
itself in the form of phlogisticated nitrous acid. As to the production
of dephlogisticated air from plants, it may be said that vegetable
substances consist chiefly of three different bases, one of which
[hydrogen], when united to dephlogisticated air, forms water; another
[carbon] fixed air; and the third phlogisticated air [nitrogen]; and
that, by means of vegetation, each of these substances are decomposed,
and yield their dephlogisticated air; and that, in burning, they again
acquire dephlogisticated air, and are restored to their pristine form.
“It seems, therefore, from what has been said, as if the phenomena of
nature might be explained very well on this principle, without the help
of phlogiston; and indeed, as adding dephlogisticated air to a body
comes to the same thing as depriving it of its phlogiston and adding
water to it, and as there are perhaps no bodies destitute of water,
and as I know no way by which phlogiston may be transferred from one
body to another, without leaving it uncertain whether water is not
at the same time transferred, it will be very difficult to determine
by experiment which of these opinions is the truest; but as the
commonly-received principle of phlogiston explains all phenomena, at
least as well as Mr. Lavoisier’s, I have adhered to that.”
Public-domain text, read in full here on John Shaqi.
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