The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“Another thing which Mr. Lavoisier endeavours to prove is that
dephlogisticated air is the acidifying principle. From what has been
explained, it appears that this is no more than saying that acids
lose their acidity by uniting to phlogiston, which, with regard to
the nitrous, vitriolic, phosphoric, and arsenical acids, is certainly
true”. “But as to the marine acid and acid of tartar, it does not
appear that they are capable of losing their acidity by any union with
phlogiston.”
Here Cavendish does not consider the question of gain of weight on
loss of phlogiston, or if he does, he must ascribe it to simultaneous
entry of water. And experimental research at that time was not far
enough advanced to enable him to decide finally as to the truth of this
hypothesis.
In his next memoir, read before the Royal Society on June 2nd, 1785,
Cavendish relates experiments on the passage of electric sparks through
air, the experiment having first been tried by Priestley. Priestley
says:[24]--“Lastly, the same effect [_i.e._ the diminution of the volume
of common air], I find, is produced by the _electric spark_, though I
had no expectation of this event when I made the experiment.” And
again:--“At the time of my former publication, I had found that taking
the _electric spark_ in given quantities of several kinds of air had a
very remarkable effect on them, that it diminished common air and made
it noxious, making it deposit its fixed air exactly like any phlogistic
process; from whence I concluded that the electric matter either is or
contains phlogiston.”
Cavendish had mentioned this process casually as one of the methods of
phlogisticating air; in beginning his second paper he says:--“I now
find that, though I was right in supposing the phlogistication of the
air does not proceed from phlogiston communicated to it by the electric
spark, and that no part of the air is converted into fixed air; yet
that the real cause of the diminution is very different from what I
suspected, and depends upon the conversion of phlogisticated air into
nitrous acid.” The apparatus he used was very simple. It consisted
of a glass siphon filled with mercury, each leg dipping into a glass
likewise containing mercury; the air was admitted by a gas-pipette into
the bend of the siphon, and on connecting the mercury in one of the
glasses with a ball placed near the prime conductor of an electric
machine, and the other with the earth, sparks could be made to pass
from the mercury in one limb to that in the other.
Public-domain text, read in full here on John Shaqi.
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