The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
The product obtained by passing sparks through air in this manner
turned litmus red, and gave rise to no cloud in lime-water, while the
air was reduced to two-thirds of its original volume; nor did the
lime-water give a precipitate on introducing some fixed air, this
showing that it had been saturated by an acid. It was found, too, that
“soap-lees,” or solution of caustic potash, if present, diminished
the volume more rapidly than did lime-water; and repeated trials
proved that “when five parts of pure dephlogisticated air were mixed
with three parts of common air, almost the whole of the air was made
to disappear.” The nitrate of potassium thus produced caused paper
soaked in it and dried to deflagrate; and it contained no sulphuric
acid. “There is no reason to think that any other acid entered into it
except the nitrous.” But it gave a precipitate with silver nitrate;
and Cavendish, suspecting that this was silver nitrite, prepared some
potassium nitrite by heating the nitrate; on comparing the white
precipitate which this solution gave with silver nitrate with that
obtained from his “soap-lees,” he found them identical. There was
therefore no “muriatic acid” present, which would have yielded chloride
of silver, of appearance somewhat similar to the nitrite.
As it had previously been shown to be probable that phlogisticated
air is nitrous air united with phlogiston, and that nitrous air is
nitric acid united with phlogiston, “we may safely conclude that in
the present experiments the phlogisticated air was enabled, by means
of the electric spark, to unite to, or form a chemical combination
with, the dephlogisticated air, and was thereby reduced to nitrous
acid, which united to the soap-lees and formed a solution of nitre; for
in these experiments the two airs actually disappeared, and nitrous
acid was actually formed in their room”. “A further confirmation of
the above-mentioned opinion is that, as far as I can perceive, no
diminution of air is produced when the electric spark is passed either
through pure dephlogisticated air or through perfectly phlogisticated
air, which indicates a necessity of a combination of these two airs to
produce the acid. Moreover, it was found in the last experiment that
the quantity of nitre procured was the same that the soap-lees would
have produced if saturated with nitrous acid; which shows that the
production of the nitre was not owing to any decomposition of the
soap-lees.”
Nothing more clearly shows the care with which Cavendish reasoned than
these last quotations. No loophole is left unstopped; every precaution
is taken to make the proof as faultless as it is possible for a proof
to be.
But this was not enough. It was necessary for Cavendish to show
that, so far as he could ascertain it experimentally, _all_ the
phlogisticated air was capable of combining with dephlogisticated air
to form nitre. This he next proceeded to do.
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