The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“As far as the experiments hitherto published extend, we scarcely know
more of the phlogisticated part of our atmosphere than that it is not
diminished by lime-water, caustic alkalies, or nitrous air; that it
is unfit to support fire or maintain life in animals; and that its
specific gravity is not much less than that of common air; so that
though the nitrous acid, by being united to phlogiston, is converted
into air possessed of these properties, and consequently, though it was
reasonable to suppose that part at least of the phlogisticated air
of the atmosphere consists of this acid united to phlogiston, yet it
might fairly be doubted whether the whole is of this kind, or whether
there are not in reality many different substances confounded together
by us under the name of dephlogisticated air. I therefore made an
experiment to determine whether the whole of a given portion of the
phlogisticated air of the atmosphere could be reduced to nitrous acid,
or whether there was not a part of a different nature from the rest,
which would refuse to undergo that change. The foregoing experiments,
indeed, in some measure decided this point, as much the greatest part
of the air let up into the tube lost its elasticity; yet, as some
remained unabsorbed, it did not appear for certain whether that was of
the same nature as the rest or not. For this purpose I diminished a
similar mixture of dephlogisticated and common air in the same manner
as before, till it was reduced to a small part of its original bulk. I
then, in order to decompound as much as I could of the phlogisticated
air which remained in the tube, added some dephlogisticated air to it,
and continued the spark until no further diminution took place. Having
by these means condensed as much as I could of the phlogisticated
air, I let up some solution of liver of sulphur to absorb the
dephlogisticated air; after which only a small bubble of air remained
unabsorbed, which certainly was not more than 1/120th of the bulk of
the phlogisticated air let up into the tube; so that, if there is
any part of the phlogisticated air of our atmosphere which differs
from the rest, and cannot be reduced to nitrous acid, we may safely
conclude that it is not more than 1/120th part of the whole.” We shall
afterwards see that this is a marvellously close estimate. There is
actually 1/84th part of the supposed nitrogen of the air which will not
combine with oxygen when sparked with it in presence of potash.
Public-domain text, read in full here on John Shaqi.
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