The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
all my experiments upon salt-peter, I found it difficult
to raise that salt by a gentle heat; and spirits of nitre,
which is drawn by means of a vehement one, has quite
different properties from crude nitre, or the supposed
volatile kind in the air, for ’tis exceeding corrosive.”[1]
Boyle then proceeds to collect and comment on the effluvia from
volcanoes and from decaying vegetables and animals, and proposes tests
for the presence of such ingredients. He even attributes the darkening
of silver chloride to its being a reagent for certain salts present
in air at one time and not at another, and draws attention to the
sulphurous smell produced by “thunder.” Farther on (p. 61) he writes:
“The generality of men are so accustomed to judge of things by their
senses, that because the air is invisible they ascribe but little to
it, and think it but one remove from nothing. And this fluid is even
by the Schoolmen considered only as a receptacle of visible bodies,
without exerting any action on them unless by its manifest qualities,
heat and moisture; tho’, for my part, I allow it other faculties,
and among them, such as are generative, maturative, and corruptive;
and that, too, in respect not only of animals and bodies of a light
texture, but even of salts and minerals.”
In another place (p. 17) he states:
“I conjecture that the atmospherical air consists of
three different kinds of corpuscles: the first, those
numberless particles which, in the form of vapours or
dry exhalations, ascend from the earth, water, minerals,
vegetables, animals, etc.; in a word, whatever substances
are elevated by the celestial or subterraneal heat, and
thence diffused into the atmosphere. The second may be
yet more subtile, and consist of those exceedingly minute
atoms the magnetical effluvia of the earth, with other
innumerable particles sent out from the bodies of the
celestial luminaries, and causing, by their impulse, the
idea of light in us. The third sort is its characteristic
and essential property, I mean permanently elastic parts.”
Boyle also relates experiments designed to “produce what appears to be
air”; and he describes the production, by the action of oil-of-vitriol
on steel filings, of “air” (now known as hydrogen) which possessed
the property of elasticity; although he failed to notice its
inflammability. He further obtained carbon dioxide by the fermentation
of raisins, and probably also hydrogen chloride in the gaseous form
by breaking a bulb containing “some good spirit-of-salt” in a vacuous
receiver.
The result of shrewd reasoning power, applied, however, to imperfect
observations, is well illustrated by the following passages:
Public-domain text, read in full here on John Shaqi.
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