The Gases of the Atmosphere: The History of Their Discovery — John Shaqi
The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“For tho’, by reason of its great thinness and of its
being, in its usual state, devoid both of taste and smell,
air seems wholly unfit to be a menstruum [or solvent]; yet
it may have a dissolving, or at least a consuming, power
on many bodies, especially such as are peculiarly disposed
to admit its operations. For the air has a great advantage
by the vast quantity of it that may come to work, in
proportion to the bodies exposed thereto.... Thus we find a
rust on copper that has been long exposed to the air.”[2]
Boyle, shortly after, describes the production of “an efflorescence of
a vitriolic nature” on marcasite (or sulphide of iron) which has been
exposed to the air; and he relates that the “ore of alum, robb’d of its
salt, will in tract of time recover it by being exposed to the air, as
we are assured by the experienced _Agricola_.”
To account for such actions, and for combustion, he proceeds (p. 81):
“The difficulty we find in keeping flame and fire
alive, tho’ but for a little time, without air, renders
it suspicious that there may be dispersed thro’ the rest
of the atmosphere some odd substance, either of a solar,
astral, or other foreign nature; on account whereof the
air is so necessary to the subsistance of flame.... It
also seems by the sudden wasting or spoiling of this
fine substance, whatever it be, that the bulk of it is
but very small in proportion to the air it impregnates
with its vertue; for after the extinction of the flame,
the air in the receiver was not visibly alter’d; and for
ought I could perceive by several ways of judging, the air
retained either all, or at least the far greatest part, of
its elasticity; which I take to be its most genuine and
distinguishing property. And this undestroyed springyness
of the air, with the necessity of fresh air to the life of
hot animals, suggest a great suspicion of some vital
substance, if I may so call it, diffused thro’ the air;
whether it be a volatile nitre, or rather some anonymous
substance, sidereal or subterraneal; tho’ not improbably of
kin to that which seems so necessary to the maintenance of
the other flames.”
The experimental part of Boyle’s work relates to the oxidation of
cuprous to cupric compounds, with the change of colour from brown to
blue or green, either in ammoniacal or in hydrochloric acid solution;
and he goes so far as to prove that two ounces of marcasites broken
into small lumps, and kept in a room “freely accessible to the air,
which was esteemed to be very pure,” for somewhat less than seven
weeks, gained above twelve grains by oxidation.
In his _Memoirs for a General History of the Air_, Boyle draws up a
programme of research, of the carrying out of which, however, there is
no record. He proposes (p. 23):
“1. To produce air by fermentation in well clos’d receivers.
Public-domain text, read in full here on John Shaqi.
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