The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
But this gives no information regarding the relative weight of an
_atom_ of argon. To ascertain this important quantity two methods
may be chosen. One is to make compounds of the element, and this
will be first considered. Since an atom of an element is defined
as the smallest amount which can exist in combination, then, if
numerous compounds of an element be examined, that one which contains
proportionally the least amount of the element may be regarded as
containing an atom, unless there are reasons to the contrary. For
example, reverting to the former instance of water, the relative
proportions by weight of oxygen and hydrogen are, in round numbers, 16
to 2. Reasons have already been given showing why its formula should
be H_{2}O and not HO; its molecule must contain two atoms of hydrogen.
But another compound of oxygen and hydrogen is known in which the
proportions are 16 parts by weight of oxygen to 1 part by weight of
hydrogen. Here also there are reasons for believing that this compound,
hydrogen peroxide, contains two atoms of hydrogen; whence it follows
that it must contain two atoms of oxygen, or 32 parts by weight to
2 parts by weight of hydrogen, and must therefore have the formula
H_{2}O_{2}. No other compound of oxygen and hydrogen is known; and it
may be stated briefly that no compound of oxygen with any element
whatever is known in which less than 16 parts by weight enters,
compared, of course, with the atomic weight of the other element or
elements in the compound. Hence 16 is accepted on this ground as the
atomic weight of oxygen.
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