The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
If now it were possible to prepare compounds of argon, similar
reasoning might be applied to them, and that compound containing least
argon would be regarded as indicating its atomic weight. Many attempts
were therefore made to induce argon to enter into combination. And
the consistent failure of these attempts led to the choice of the
name “argon” or “idle” for the newly discovered element. The methods
employed to prepare argon free from nitrogen, namely, by exposing the
mixed gases to the action of oxygen in a discharge of electric sparks,
and by passing them over red-hot magnesium, show that it cannot be
induced to combine with one of the most electro-negative of elements,
oxygen, and one of the most electro-positive, magnesium. It also
refuses to combine with hydrogen or with chlorine when sparked with
these gases; nor is it absorbed or altered in volume by passage through
a red-hot tube along with the vapours of phosphorus, sulphur,
tellurium, or sodium. Red-hot caustic soda, or a red-hot mixture of
soda and lime, which attacks the exceedingly refractory metal platinum,
was without action on argon. The combined influence of oxygen and an
alkali in the shape of fused potassium nitrate or red-hot peroxide of
sodium was also without effect. Gold would, however, have resisted
such action, but it would have been attacked by the next agent tried,
viz. persulphide of sodium and calcium. This mixture was exposed at a
red-heat to a current of argon, again without result. Nascent chlorine,
or chlorine at the moment of liberation, obtained from a mixture of
nitric and hydrochloric acids, and from permanganate of potassium
and hydrochloric acid, was without action. A mixture of argon with
fluorine, the most active of all the elements, was exposed to a rain
of electric sparks by M. Moissan, the distinguished chemist who first
succeeded in preparing large quantities of fluorine in a pure state,
without his observing any sign of chemical combination.
An attempt was also made to cause argon to combine with carbon by
making an electric arc between two rods of carbon in an atmosphere of
argon. It was at first believed that combination had taken place, for
expansion occurred, the final volume of gas being larger than the
volume taken; but subsequent experiments have shown that the expansion
was due to the formation of some oxide of carbon from the oxygen
adhering to the carbon rods. On absorption of this oxide by the usual
absorbent, a mixture of cuprous chloride and ammonia, the argon was
recovered unchanged.
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