The Growth of a Crystal: Being the eighteenth Robert Boyle lectureMiers, Henry Alex
Science
The Growth of a Crystal: Being the eighteenth Robert Boyle lecture
Miers, Henry Alex
Crystallography
Now let me pass to another series of researches which were conducted by
Miss ISAAC and myself for a few years before I left Oxford and have
since been carried on by her with conspicuous success. Still
experimenting with the same apparatus, and endeavouring to trace how a
solution changes in strength while it is crystallizing, we came across
some curious and unexpected results. It is, of course, well known that
if a crystal, say of alum, is placed in a weak solution of alum it is
dissolved, and only has the effect of making the solution stronger, but
that at last a stage is reached at which the solution becomes
‘saturated’ and can dissolve no more, just as a stage is reached at
which a soaking sponge will hold no more water. At this point a crystal,
if put into it, remains unchanged. But it is quite easy to make the
solution still stronger, not by adding alum to it, but by taking water
away from it by evaporation: it then becomes oversaturated or
‘supersaturated’, and now a crystal of alum dipped into the liquid will
at once begin to grow and to make the solution weaker. In fact, this is
an unfailing test by which we can tell whether a solution is saturated
or supersaturated; and, more than this, until a bit of solid crystal
gets into it the liquid does not crystallize. Keep it in a closed vessel
so that no speck of alum can fall into it, and it will remain liquid for
weeks or years or as long as you please. But let the smallest possible
grain of an alum crystal fall into it, and crystallization will be
started; inoculate it with an invisible germ of alum dust, such as must
be flying about in the air of any room where dry alum is or has been
kept, and you will see the life and growth of a crystal begin when that
germ is introduced. This is the most extraordinarily sensitive test, and
one that can easily be applied.
In many of our experiments we found that during the first day when we
were working with some new substance it would not crystallize from an
exposed solution; but on the second day, when the air of the laboratory
had become impregnated with crystal germs, an exposed solution would
begin to crystallize at once.
Dr. TUTTON, one of the most accomplished investigators of crystals,
whose refined and beautiful researches were for many years carried on in
Oxford, has fully described these effects in his two books on crystals
just published, and confirms them from his own experience.
Public-domain text, read in full here on John Shaqi.
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