The Growth of a Crystal: Being the eighteenth Robert Boyle lectureMiers, Henry Alex
Science
The Growth of a Crystal: Being the eighteenth Robert Boyle lecture
Miers, Henry Alex
Crystallography
Now, Miss ISAAC and I have found in the course of our researches that,
as the solution becomes stronger and stronger—say, by the evaporation of
some of its water, it continues to be in the ordinary state of
supersaturation in which it does not crystallize save by inoculation
with a germ of solid alum crystal, but at last it suddenly reaches a
condition in which it can crystallize spontaneously, and at this moment
it is enough to stir or shake the solution, and you will at once witness
the birth of thousands of tiny crystals which appear as a cloud in the
liquid and begin to grow rapidly.
A very easy way in which to make this experiment is to dip a clean
needle into a drop of evaporating solution on a glass plate and to
scratch the glass on which the drop lies: for a time nothing happens,
and then suddenly, as the liquid passes into the new condition, a chain
of tiny crystals appears along the line of scratch.
That this suspended crystallization has a fixed limit was suspected, and
had been predicted by the German chemist OSTWALD, but could never be
proved until we made our experiments, and it was Mr. HARTLEY who first
helped us to interpret our results. He has subsequently, with his
pupils, made a number of investigations on the same subject.
I can show you the two conditions in one and the same drop by using a
solution of common potassium bichromate. Crystals begin to grow at the
edge of the drop where the liquid first becomes sufficiently strong, and
continue to grow slowly in the evaporating liquid which is only slightly
supersaturated. But in a few moments other parts of the drop which are
thinner become so strongly supersaturated that they begin to crystallize
spontaneously; and there you can witness the birth of new crystals which
grow rapidly in all directions, because they are growing in a solution
which is much stronger than that in which the first crystals are growing
slowly.
Does not all this set one thinking? What is taking place we cannot tell,
but we can only think of it as in some way analogous to the birth of a
cloud; and in both instances we have to picture to ourselves minute
invisible particles, of whose shape and size we know nothing, coming
together and coalescing till they grow into a drop or a crystal that we
can see. But why they do not begin to coalesce as soon as the liquid is
supersaturated it is difficult to say. We have to conceive the alum
solution as made up of moving particles of alum and of water, and it may
be that the particles are constantly coalescing into minute groups, but
as rapidly being broken up again, until a moment arrives at which the
alum particles are sufficiently dense to cohere permanently; but how
they attract one another and arrange themselves into the wonderful
structure which makes a crystal, of this we are entirely ignorant. The
question brings us back again to our initial mystery, how does the
crystal actually grow?
Public-domain text, read in full here on John Shaqi.
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